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Tetraphenylantimony Pentafluorobenzoate and Tetra-p-Tolylantimony Nitrate: Syntheses and Structures

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Abstract

The reactions of pentaarylantimony with antimony derivatives Ar3SbX2(Ar = Ph or p-Tol and X = OC(O)C6F5or NO3) afford tetraphenylantimony pentafluorobenzoate (Ph4SbOC(O)C6F5) and tetra-p-tolylantimony nitrate (p-Tol4SbONO2). The compounds obtained were structurally characterized by X-ray diffraction analysis. The Sb atom in Ph4SbOC(O)C6F5has a distorted trigonal-bipyramidal environment with an axial perfluorobenzoate group. The trigonal-bipyramidal coordination of antimony in p-Tol4SbONO2is strongly distorted, with the O atom of the nitrato group lying in the axial plane.

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Authors and Affiliations

  1. Blagoveshchensk State Pedagogical University, Blagoveshchensk, Russia

    V. V. Sharutin, O. K. Sharutina, E. A. Bondar', A. P. Pakusina, N. Yu. Adonin, V. F. Starichenko, G. K. Fukin & L. N. Zakharov

  2. Novosibirsk Institute of Organic Chemistry, Siberian Division, Russian Academy of Sciences, pr. Akademika Lavrent'eva 8, Novosibirsk, 630090, Russia

    V. V. Sharutin, O. K. Sharutina, E. A. Bondar', A. P. Pakusina, N. Yu. Adonin, V. F. Starichenko, G. K. Fukin & L. N. Zakharov

  3. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, ul. Tropinina 49, Nizhnii Novgorod, 603600, Russia

    V. V. Sharutin, O. K. Sharutina, E. A. Bondar', A. P. Pakusina, N. Yu. Adonin, V. F. Starichenko, G. K. Fukin & L. N. Zakharov

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  1. V. V. Sharutin
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Sharutin, V.V., Sharutina, O.K., Bondar', E.A. et al. Tetraphenylantimony Pentafluorobenzoate and Tetra-p-Tolylantimony Nitrate: Syntheses and Structures. Russian Journal of Coordination Chemistry 27, 393–397 (2001). https://doi.org/10.1023/A:1011335724711

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