Skip to main content
SpringerLink
Log in

Acidity function of methanesulfonic acid solutions in ethyl acetate

Russian Chemical Bulletin volume 50, pages 1003–1007 (2001)Cite this article

Abstract

The acidity function of solutions of methanesulfonic acid (MSA) in ethyl acetate (EA) was measured by the indicator method at 25 °C in the 0.4—100% concentration range. Molecular complexes formed by MSA and EA show a higher ionizing activity than H5O2 + ions. The relative ionizing activity of the MSA·EA complexes and ion pairs formed by MSA and DMF was determined.

This is a preview of subscription content, access via your institution.

Access options

Buy single article

Instant access to the full article PDF.

USD 39.95

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

References

  1. G. V. Yukhnevich, E. G. Tarakanova, V. D. Maiorov, and N. B. Librovich, Usp. Khim. 1995, 64, 963 [Russ. Chem. Rev., 1995, 64, 963 (Engl. Transl.)].

    Google Scholar 

  2. A. P. Kirilova, V. D. Maiorov, A. I. Serebryanskaya, N. B. Librovich, and E. N. Gur'yanova, Izv. Akad. Nauk SSSR, Ser. Khim., 1985, 1493 [Bull. Acad. Sci. USSR, Div. Chem. Sci., 1985, 34, 1366 (Engl. Transl.)].

  3. V. V. Burdin, I. S. Kislina, V. D. Maiorov, S. G. Sysoeva, and N. B. Librovich, Izv. Akad. Nauk, Ser. Khim., 1998, 2484 [Russ. Chem. Bull., 1998, 47, 2404 (Engl. Transl.)].

    Google Scholar 

  4. V. D. Maiorov and I. S. Kislina, Khim. Fizika, 1992, 11, 660 [Chem. Phys. Reports, 1993, 11, 956 (Engl. Transl.)].

    Google Scholar 

  5. V. V. Burdin, V. D. Maiorov, and N. B. Librovich, Izv. Akad. Nauk, Ser. Khim., 2000, 292 [Russ. Chem. Bull., Int. Ed., 2000, 49, 295].

    Google Scholar 

  6. N. B. Librovich, V. V. Burdin, V. D. Maiorov, and I. S. Kislina, Khim. Fizika, 2000, 19, 41 [Chem. Phys. Reports, 2000, 19 (Engl. Transl.)].

    Google Scholar 

  7. I. S. Kislina and S. G. Sysoeva, Izv. Akad. Nauk, Ser. Khim., 1999, 1940 [Russ. Chem. Bull., 1999, 48, 1916 (Engl. Transl.)].

  8. C. H. Rochester, Acidity Functions, Academic Press, London-New York, 1970, Ch. 6.

    Google Scholar 

  9. M. I. Vinnik, Kinet. Katal., 1980, 21, 136 [Kinet. Catal., 1980, 21 (Engl. Transl.)].

    Google Scholar 

  10. M. I. Vinnik, Izv. Akad. Nauk SSSR, Ser. Khim., 1973, 998 [Bull. Acad. Sci. USSR, Div. Chem. Sci., 1973, 22 (Engl. Transl.)].

  11. R. A. Cox and K. Jates, Canad. J. Chem., 1983, 61, 2225.

    Google Scholar 

  12. I. S. Kislina, S. G. Sysoeva, N. B. Librovich, O. N. Temkin, I. L. Eremenko, and S. E. Nefedov, Dokl. Akad. Nauk, 1998, 360, 649 [Dokl. Chem., 1998, 360, 106 (Engl. Transl.)].

    Google Scholar 

  13. V. D. Maiorov, I. S. Kislina, G. I. Voloshenko, and N. B. Librovich, Izv. Akad. Nauk, Ser. Khim., 2000, 1537 [Russ. Chem. Bull., Int. Ed., 2000, 49, 1526].

    Google Scholar 

  14. I. S. Kislina, S. G. Sysoeva., and O. N. Temkin, Izv. Akad. Nauk, Ser. Khim., 1996, 77 [Russ. Chem. Bull., 1996, 45, 69 (Engl. Transl.)].

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. N. N. Semenov Institute of Chemical Physics, Russian Academy of Sciences, 4 ul. Kosygina, 119911, Moscow, Russian Federation

    I. S. Kislina &  Sysoeva

Authors
  1. I. S. Kislina
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Sysoeva
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and Permissions

About this article

Cite this article

Kislina, I.S., Sysoeva Acidity function of methanesulfonic acid solutions in ethyl acetate. Russian Chemical Bulletin 50, 1003–1007 (2001). https://doi.org/10.1023/A:1011309016786

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/A:1011309016786

search

Navigation