Abstract
Co(Cyclohexylamine)2Ni(CN)4 and Cd(Cyclohexylamine)2Ni(CN)4 host compounds have been prepared in powder form. The spectral data suggest that these complexes are similar in structure to the Hofmann-dma-type hosts. The sorption processes of the aromatic guests (benzene, toluene, o-, m-, p-xylene, naphthalene, 1,2-, 1,3-dichlorobenzene and 1,4-dibromobenzene) inthese hosts have been examined at room temperature by gravimetric and spectroscopic measurements. The desorption of the benzene guest against time has been measured. The host structures change on inclusion of the guests and recover after liberation. The host complexes have been suggested as sorbents for isomeric separations.
Similar content being viewed by others
References
R.F. Evans, O. Ormrod, B.B. Goalby, and L.A.K. Stavely: J. Chem. Soc. 3346 (1950).
U.S. Patent, 2, 732, 413 (1956).
T. Iwamoto: The Hofmann-type and Related Inclusion compounds (Inclusion compounds, Vol. 4, J.L. Atwood, J.E.D. Davies and D.D. MacNicol (eds.), pp. 29-57, Academic Press (1984).
S. Nishikiori and T. Iwamoto: Chem. Lett. 1035 (1982).
Y. Mathey and C. Mazieres: Can. J. Chem. 52, 3637 (1974).
S. Akyüz, A.B. Dempster, R.L. Morehouse, and S. Susuki: J. Mol. Struct. 17, 105 (1973).
S. Akyüz, A.B. Dempster, and R.L. Morehouse: Spectrochim. Acta 30A, 1183 (1974).
S. Akyüz, A.B. Dempster, and R.L. Morehouse: Spectrochim. Acta 30A, 1189 (1974).
S. Bayarı, Z. Kantarcı, and S. Akyüz: J. Mol. Struct. 351, 19 (1995).
N. Karacan, Z. Kantarcı, and S. Akyüz: Spectrochim. Acta A52, 771 (1996).
R.L. McCullough, L.H. Jones, and G.A. Croaby, Spectrochim. Acta 16, 929 (1960).
A.O. Diallo, N.V. Thanh, and I. Rossi, Spectrochim. Acta 43A, 415 (1987).
S. Akyüz and J.E.D. Davies: J. Mol. Struct. 97, 457 (1982).
S. Bayar, C. Bayrak, and Z. Kantarcı: J. Incl. Phenom. 38, 23 (2000).
D.A. Thornton: J. Coord. Chem. 24, 261 (1991).
T. Iwamoto, J. Incl. Phenom. 24, 61 (1996).
P.C. Painter and J.L. Koenig: Spectrochim. Acta. 33A, 1003 (1977).
A.P. Hitchcock and J.D. Laposa: J.Mol.Spectrosc. 54, 223 (1975).
E. Kasap and A. Özbay: J. Incl. Phenom. 28, 335 (1997).
J.H.S. Green: Spectrochim.Acta. 26A, 1913 (1970).
J.H.S. Green: Spectrochim. Acta. 26A, 1523 (1970).
S. Sağlam, T.R. Sertbakan, E. Kasap, and Z. Kantarcı: J. Mol. Struct. 482-483, 69 (1999).
J.H.S. Green: Spectrochim. Acta. 26A, 1503 (1970).
T.R. Sertbakan, E. Kasap, and Z. Kantarcı: J. Mol. Struct. 482-483, 75 (1999).
J.R. Schever and J.C. Evans: Spectrochim. Acta 19, 1739 (1963).
E.R. Lippincott and E.J. O'Reilly: J. Chem. Phys. 23, 238 (1955).
E. Kasap and Z. Kantarcı: J. Incl. Phenom. 23, 1 (1995).
N. Ekici, Z. Kantarcı, and S. Akyüz: J. Incl. Phenom. 10, 9 (1991).
E. Kasap and Z. Kantarcı: J. Incl. Phenom. 20, 33 (1995).
Z. Kantarcı and C. Bayrak: J. Incl. Phenom. 30, 59 (1998).
S. Bayarı, Z. Kantarcı, and S. Akyüz: J. Incl. Phenom. 17, 291 (1998).
E. Ruiz, J.J. Novoa, and S. Alvarez, J. Phys. Chem. 99, 2296 (1995).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Kantarci, Z., Bülbül, M.M. Infrared Spectroscopic and Gravimetric Studies on the Dicyclohexylaminemetal(II) Tetracyanonickellate(II) Host-aromatic Guest Systems. Journal of Inclusion Phenomena 40, 105–116 (2001). https://doi.org/10.1023/A:1011150718904
Issue Date:
DOI: https://doi.org/10.1023/A:1011150718904