Skip to main content
SpringerLink
Log in

Structure and Magnetic Properties of Mn(II) Complexes with Enaminoketone Derivatives of 3-Imidazoline Nitroxide

  • Published:
Journal of Structural Chemistry Aims and scope Submit manuscript

Abstract

The crystal structures of two manganese complexes with the enaminoketone derivatives of 3-imidazoline nitroxide: MnL COOMe2 (layered polymeric) and MnL CF32 (DMF)2 (molecular) have been determined. The polymer structure of MnL COOMe2 is the result of direct coordination of the nitroxyl O atoms of the neighboring bischelate fragments by the Mn atoms. This forms heterospin exchange clusters >N⋅-O–Mn(II)–O-N< with strong antiferromagnetic interactions between the odd electrons of the paramagnetic centers. The structure of MnL CF32 (DMF)2 is characterized by ligand cis-coordination in the octahedral coordination polyhedron. Due to the molecular nature of the complex, the solid compound has only weak ferromagnetic intramolecular indirect exchange interactions. The charge states of atoms in coordination units was confirmed by X-ray photoelectron data.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. V. N. Ikorskii, V. I. Ovcharenko, Yu. G. Shvedenkov, et al., Inorg. Chem., 37, 4360-4367 (1998).

    Google Scholar 

  2. V. I. Ovcharenko, V. N. Ikorskii, G. V. Romanenko, et al., Synth. Met., 85, 1639-1642 (1997).

    Google Scholar 

  3. V. I. Ovcharenko and R. Z. Sagdeev, Usp. Khim., 68, 381-400 (1999).

    Google Scholar 

  4. V. I. Ovcharenko, Yu. G. Shvedenkov, R. N. Musin, and V. N. Ikorskii, Zh. Strukt. Khim., 40, No. 1, 36-43 (1999).

    Google Scholar 

  5. V. I. Ovcharenko, G. V. Romanenko, V. N. Ikorskii, et al., Inorg. Chem., 33, 3370-3381 (1994).

    Google Scholar 

  6. K. É. Vostrikova, V. I. Ovcharenko, G. V. Romanenko, et al., Zh. Neorg. Khim., 37, 1755-1772 (1992).

    Google Scholar 

  7. V. N. Ikorskii, V. I. Ovcharenko, K. É. Vostrikova, et al., ibid., 37, 1177-1183 (1992).

    Google Scholar 

  8. V. I. Nefedov, X-Ray Photoelectron Spectroscopy of Chemical Compounds [in Russian], Khimiya, Moscow (1984), p. 253.

    Google Scholar 

  9. V. I. Nefedov, Itogi Nauki Tekh., 1, 147 (1973).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Russian Academy of Sciences, International Tomography Center, Siberian Branch, Russia

    E. Yu. Fursova, V. I. Ovcharenko & Yu. G. Shvedenkov

  2. Siberian Branch, Russian Academy of Sciences, Institute of Inorganic Chemistry, Russia

    G. V. Romanenko, V. N. Ikorskii, I. P. Asanov & L. N. Mazalov

Authors
  1. E. Yu. Fursova
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. V. I. Ovcharenko
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. G. V. Romanenko
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. V. N. Ikorskii
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Yu. G. Shvedenkov
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. I. P. Asanov
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. L. N. Mazalov
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Fursova, E.Y., Ovcharenko, V.I., Romanenko, G.V. et al. Structure and Magnetic Properties of Mn(II) Complexes with Enaminoketone Derivatives of 3-Imidazoline Nitroxide. Journal of Structural Chemistry 42, 251–260 (2001). https://doi.org/10.1023/A:1010559117135

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/A:1010559117135

Keywords

Search

Navigation