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Structural Effects of Intercalation in [LiAl2(OH)6]Cl ⋅ xH2Os (1H, 7Li, 27Al NMR)

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Abstract

1H, 7Li, and 27Al NMR was used to study [LiAl2(OH)6]Cl ⋅ xH2O systems (x = 0, 1.6, and 2.8). At larger x values, the amplitude of the librational motion of the hydroxyl groups increases and the chloride ions are disordered, while the localization of the lithium and aluminum ions does not change.

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References

  1. A. P. Nemudry, V. P. Isupov, N. P. Kotsupalo, and V. V. Boldyrev, Izv. Sib. Otd. Ross. Akad. Nauk, Ser. Khim. Nauk, 11, No. 4, 28-32 (1984).

    Google Scholar 

  2. A. P. Nemudry, V. P. Isupov, N. P. Kotsupalo, and V. V. Boldyrev, React. Sol., 1, 221-226 (1986).

    Google Scholar 

  3. A. P. Nemudry, V. P. Isupov, N. P. Kotsupalo, and V. V. Boldyrev, Neorg. Khim., 31, No. 5, 651-653 (1986).

    Google Scholar 

  4. A. P. Nemudry, I. A. Poroshina, V. P. Isupov, et al., Izv. Sib. Otd. Ross. Akad. Nauk, Ser. Khim. Nauk, 2, 48-52 (1987).

    Google Scholar 

  5. A. V. Besserguenev, A. M. Fogg, R. J. Francis, et al., Chem. Mater., No. 9, 241-247 (1997).

    Google Scholar 

  6. R. D. Goodenough, US Patent No. 2964381, Recovery of Lithium, Refer. Zh. Khim., 3K61 (1962).

  7. M. P. Neipert and C. K. Bon, US Patent No. 3306700, Method of Lithium Recovery, Refer. Zh. Khim., 10L62P (1969).

  8. J. M. Lee and W. C. Bauman, US Patent No. 4116856, Recovery of Lithium from Brines, Refer. Zh. Khim., 10L41P (1979).

  9. V. P. Isupov, N. P. Kotsupalo, A. P. Nemudry, and L. T. Menzeres, in: Adsorption and Its Applications in Industry and Environmental Protection. Studies in Surface and Catalysis, Dabrowski (ed.), Elsevier (1999), pp. 621-652.

  10. V. P. Isupov, Chemical Sciences Doctoral Dissertation, Institute of Solid State Chemistry and Mechanochemistry, Novosibirsk (1998).

  11. V. P. Isupov, S. G. Kozlova, S. P. Gabuda, and L. Ė. Chupakhina, Dokl. Ross. Akad. Nauk, 355, No. 6, 774-776 (1997).

    Google Scholar 

  12. V. P. Isupov, S. P. Gabuda, S. G. Kozlova, and L. Ė. Chupakhina, Zh. Strukt. Khim., 39, No. 3, 448-452 (1998).

    Google Scholar 

  13. A. Abragam, Nuclear Magnetism [Russian translation], IL, Moscow (1963).

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Authors and Affiliations

  1. Siberian Branch, Russian Academy of Sciences, Institute of Inorganic Chemistry, Russia

    S. G. Kozlova & S. P. Gabuda

  2. Institute of Solid State Chemistry and Mechanochemistry, Siberian Branch, Russian Academy of Sciences, Russia

    V. P. Isupov & L. É. Chupakhina

Authors
  1. S. G. Kozlova
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  2. S. P. Gabuda
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  3. V. P. Isupov
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  4. L. É. Chupakhina
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Kozlova, S.G., Gabuda, S.P., Isupov, V.P. et al. Structural Effects of Intercalation in [LiAl2(OH)6]Cl ⋅ xH2Os (1H, 7Li, 27Al NMR). Journal of Structural Chemistry 42, 189–192 (2001). https://doi.org/10.1023/A:1010490629431

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  • DOI: https://doi.org/10.1023/A:1010490629431

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