Skip to main content
SpringerLink
Log in

Effect of Chlorine Released during Hydrodechlorination of Chlorobenzene over Pd, Pt and Rh Supported Catalysts

  • Published:
Reaction Kinetics and Catalysis Letters Aims and scope Submit manuscript

Abstract

Chlorobenzene hydrodechlorination in liquid phase has been studied. Chlorine released during the reaction inhibits conversion in large metallic particles. It was found comparing the behavior of Pd/SiO2, Pd/Al2O3 and Pd/C catalysts that the support plays the role of a chlorine trap. The activity for Pt, Rh and Pd at similar dispersions corresponds to the chlorine adsorption affinity of the metals.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

REFERENCES

  1. P.N. Rylander: Catalytic Hydrogenation over Platinum Metals, Chap. 24. AcademicPress, New York 1967.

    Google Scholar 

  2. S. Kovenklioglu, Z. Cao, D. Shah, R.J. Farrauto, E.N. Balko: J. AIChE, 38, 1003 (1992).

    Google Scholar 

  3. E.N. Balko, E. Przybylski, F.V. Trentini: Appl. Catal., B, 2, 1 (1993).

    Google Scholar 

  4. J. L. Benitez, G. Del Angel: React. Kinet. Catal. Lett., 66 , 13 (1999).

    Google Scholar 

  5. C. Grittini, M. Malcomson, Q. Fernando, N. Korte: Environ. Sci. Technol., 29, 2898(1995).

    Google Scholar 

  6. J.B. Hoke, A. Gramiccioni, E.N. Balko: Applied Catalysis B: Environmental, 1 , 285 (1992).

    Google Scholar 

  7. C.N. Satterfield: Mass Transfer in Heterogeneous CatalysisI, p. 108. MIT Press, Cambridge MA, 1960.

    Google Scholar 

  8. R.M. Koros, J. Nowak: Chem. Eng. Sci., 22, 470 (1967).

    Google Scholar 

  9. M. Boudart, W.C. Cheng: J. Catal., 106, 134 (1987).

    Google Scholar 

  10. B. Coq, G. Ferrat, F. Figueras: J. Catal., 101, 434 (1986).

    Google Scholar 

  11. M.A. Aramendia, V. Borau, I.M. Garcia, C. Jimenez, F. Lafont, A. Marinas, J.M. Marinas, F.J. Urbano: J. Catal., 187, 392 (1999).

    Google Scholar 

  12. R.J. Harper, C. Kembal: Trans. Faraday Soc., 65, 2224 (1969).

    Google Scholar 

  13. J. Sepulveda, N. Figoli: React. Kinet. Catal. Left., 53, 155 (1994); M.D. Somolikov, A. S. Belyi, D.I. Kiryanov, V.Yu. Borovkov, A.V. Zaitzev, V.K. Duplyakin, V.B. Kazanskii:React. Kinet. Catal. Lett., 53, 161 (1994).

    Google Scholar 

Download references

Authors
  1. José Luis Benitez
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Gloria Del Angel
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Benitez, J.L., Del Angel, G. Effect of Chlorine Released during Hydrodechlorination of Chlorobenzene over Pd, Pt and Rh Supported Catalysts. Reaction Kinetics and Catalysis Letters 70, 67–72 (2000). https://doi.org/10.1023/A:1010354430406

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/A:1010354430406

Search

Navigation