Skip to main content
SpringerLink
Log in

Kinetics of Addition of Diethylamine to Oligo[(2-Acryloyloxy-5-Methyl-1,3-Phenylene)-Methylene] Catalyzed by Lithium Diethylamide

  • Published:
Reaction Kinetics and Catalysis Letters Aims and scope Submit manuscript

Abstract

The kinetics of addition reaction of diethylamine to vinyl groups of oligo[(2-acryloyloxy-5-methyl-1,3-phenylene)methylene] in benzene with excess amine in the presence of lithium diethylamide as catalyst has been investigated. The reaction rate, was found to be expressed as: V = k [CH2=CH-][Et2NLi] with the ratio of [Et2NH]o to [Et2NLi]o being 5. Second-order rate constants for addition and the activation energy have been determined.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

REFERENCES

  1. N. Imai, T. Narita, T. Tsuruta: Tetrahedron Lett., 3517 (1971).

  2. T. Narita,. N. Imai, T. Tsuruta: Bull. Chem. Soc. Jpn.., 46, 1242 (1973).

    Google Scholar 

  3. T. Narita, T. Yamaguchi, T. Tsuruta: Bull. Chem. Soc. Jpn., 46, 3825 (1973).

    Google Scholar 

  4. T. Tsuruta, T. Narita, Y. Nitadori, T. Irie: Makromol. Chem., 177, 3235 (1976).

    Google Scholar 

  5. J. Yukawa, K. Kataoka, Y. Nitadori, T. Tsuruta: Polym. J., 11, 165 (1979).

    Google Scholar 

  6. Y. Nitadori, T. Tsuruta: Makromol. Chem., 180, 1877 (1979).

    Google Scholar 

  7. T. Nishimura, M. Maeda, Y. Nitadori, T. Tsuruta: Makromol. Chem., 183, 29 (1981).

    Google Scholar 

  8. X. Li, M. Maeda, T. Tsuruta: Makromol. Chem., 182, 2445 (1981).

    Google Scholar 

  9. H. Kämmerer, N. Onder: Makromol. Chem., 11, 67 (1968).

    Google Scholar 

  10. Z. Shen, J.R. Schlup: J. Appl. Polym. Sci., 67, 267 (1998)

    Google Scholar 

  11. R.N. Morisson, R.N. Boyd: Organic Chemistry, Vol. 2, p. 73, Third Edition. Allyn and Bacon, Inc, Boston, Massachusetls 1973.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Physical Chemistry of Polymers, Technical University of Łódź, 90-924, Łódź, Poland

    Roman Jantas & Zbigniew Draczyński

Authors
  1. Roman Jantas
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Zbigniew Draczyński
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Jantas, R., Draczyński, Z. Kinetics of Addition of Diethylamine to Oligo[(2-Acryloyloxy-5-Methyl-1,3-Phenylene)-Methylene] Catalyzed by Lithium Diethylamide. Reaction Kinetics and Catalysis Letters 70, 251–257 (2000). https://doi.org/10.1023/A:1010324429922

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/A:1010324429922

Search

Navigation