Abstract
A kinetic study on triphenylphosphine oxidation with VOCl3 was carried out in CCl4 and THF. The different mechanisms were elucidated; oxygen was activated dissociatively on solid vanadium complex in CCl4, while oxygen was coordinated molecularly on soluble vanadium complex in THF.
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Kanai, H., Osaka, S. Oxidation of Triphenylphosphine by Vanadium Oxytrichloride. Reaction Kinetics and Catalysis Letters 70, 105–112 (2000). https://doi.org/10.1023/A:1010314800363
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DOI: https://doi.org/10.1023/A:1010314800363