Skip to main content
SpringerLink
Log in

Evaluation of Desorption Energy Distributions from TPD Spectra on a Heterogeneous Solid Surface

  • Published:
Journal of Thermal Analysis and Calorimetry Aims and scope Submit manuscript

Abstract

The condensation approximation (CA) and numerical regularization procedure (RP) methods used to solve a Fredholm integral equation of the first kind describing the adsorption equilibria on a heterogeneous solid surface under isothermal conditions have been adopted in the present study to evaluate desorption energy distributions from temperature-programmed desorption (TPD) spectra. From comparisons of the computational results obtained by means of these methods on the basis of simulated TPD spectra, it follows that the CA gives stable solutions for wide desorption energy distributions and it can be used successfully for calculations from wide and clear resolved peaks in the TPD spectra. The use of the RP is more advantageous for acquisition of the distributions from closely related narrow peaks in the TPD spectra.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. G. F. Cerafolini and N. Re, J. Collolid Interface Sci., 174 (1995) 428.

    Article  Google Scholar 

  2. V. I. Bogillo, L. S. Pirnach and A. Dabrowski, Langmuir, 13 (1997) 928.

    Article  CAS  Google Scholar 

  3. A. N. Tikhonov, Dokl. Akad. Nauk USSR, 39 (1943) 195.

    Google Scholar 

  4. B. Hunger, M. V. Szombathely, J. Hoffmann and P. Brauer, J. Thermal Anal., 44 (1995) 293.

    CAS  Google Scholar 

  5. A. S. Leonov and A. G. Jagola, Vestn+ Moscow Univ., Ser. 3: Fiz., Astron., 36 (1995) 28.

    Google Scholar 

  6. V. I. Bogillo and P. Staszczuk, J. Therm. Anal. Cal., 55 (1999) 493

    Article  CAS  Google Scholar 

  7. V. I. Bogillo, D. Glazewski and P. Staszczuk, in Proc. of III. Intern. Symp. Effects of Surface Heterogeneity in Adsorption and Catalysis on Solids, Torun, Poland, Aug. 9–16, 1998, 22.

Download references

Author information

Authors and Affiliations

  1. Institute of Surface Chemistry, National Academy of Sciences, 31 Prospect Nauki, 252022, Kiev, Ukraine

    V. I. Bogillo & V. P. Shkilev

Authors
  1. V. I. Bogillo
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. V. P. Shkilev
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Bogillo, V.I., Shkilev, V.P. Evaluation of Desorption Energy Distributions from TPD Spectra on a Heterogeneous Solid Surface. Journal of Thermal Analysis and Calorimetry 55, 483–492 (1999). https://doi.org/10.1023/A:1010193802672

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/A:1010193802672

Search

Navigation