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Decomposition of Cyclohexyl-t-butyl-Dimethylammonium Tetraphenylborate: Synthesis and kinetics

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Abstract

A new compound cyclohexyl-t-butyldimethylammonium tetraphenylborate, [C6H11N(CH3)2(C(CH3)3)]BPh4 has been prepared, and its decomposition mechanism was studied by TG. The IR spectra of the products of thermal decomposition were examined at every stage. Kinetic analysis for the first stage of thermal decomposition process was obtained by TG and DTG curves, and kinetic parameters were obtained from the analysis of the TG-DTG curves with integral and differential equations. The most probable kinetic function was suggested by comparison of kinetic parameters.

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Author notes

  1. S. Jiang

    Present address: Kaifaqu School, Weihai, Shandong Province, 264209, P. R. China

Authors and Affiliations

  1. Department of Natural Science, Harbin Institute of Technology, Weihai Campus, Weihai, Shandong Province, 264209, P. R. China

    B. Zhou, S. Jiang & D. Zhou

  2. Department of Chemistry, Shandong Yantai Teacher's College, Yantai, Shandong Province, 264025, P. R. China

    L. Zou & X. Wang

  3. Department of Chemistry, Shandong Normal University, Jinan, Shandong Province, 250014, P. R. China

    D. Wang, J. Liu & S. Shang

Authors
  1. B. Zhou
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  2. S. Jiang
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  3. L. Zou
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  4. X. Wang
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  5. D. Wang
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  6. J. Liu
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  7. S. Shang
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  8. D. Zhou
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Zhou, B., Jiang, S., Zou, L. et al. Decomposition of Cyclohexyl-t-butyl-Dimethylammonium Tetraphenylborate: Synthesis and kinetics. Journal of Thermal Analysis and Calorimetry 58, 487–493 (1999). https://doi.org/10.1023/A:1010184028318

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  • DOI: https://doi.org/10.1023/A:1010184028318

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