Abstract
The inorganic ion-exchanger α-zirconium phosphate was synthesized by the sol-gel method and its properties relating to the exchange of Cd2+ and the intercalation of CdS particles were studied. The Cd2+-exchange process is a fast process and the material obtained exhibits an increased interlayer distance d with respect to its precursor (9.56 vs. 7.56 Å). The resulting Cd-containing material was exposed to aH2S gas flow to give CdS particles in the exchanger. The zirconium phosphate containing CdS particles still possesses a layered structure, with a pattern almost identical to that of the initial ion-exchanger precursor. Moreover, the material may exchange further Cd2+ and hence lead to a higher CdS particle content. The thermal behavior of this ion-exchangers containing Cd2+ or CdS particles was studied.
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Ferragina, C., Cafarelli, P. & Di Rocco, R. Incorporation of Cadmium Ions and Cadmium Sulfide Particles into Sol-gel Zirconium Phosphate. Synthesis, thermal behavior and X-ray characterization. Journal of Thermal Analysis and Calorimetry 63, 709–721 (2001). https://doi.org/10.1023/A:1010183819410
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DOI: https://doi.org/10.1023/A:1010183819410