Abstract
The enthalpies of acid-base interactions in solutions of the complexons iminodiacetic acid, nitryltriacetic acid, ethylenediaminetetraacetic acid and their phosphorylated analogues were determined with an isothermal-shell calorimeter with automatic temperature recording in a background of different electrolytes in the temperature range 283–328 K.
The concepts of Gurney were used to analyse the thermodynamic characteristics of the reactions.
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Kochergina, L.A., Vasil'ev, V.P. Peculiarities of Thermochemical Investigations of Acid-Base Equilibria in Complexon Solutions. Journal of Thermal Analysis and Calorimetry 54, 317–322 (1998). https://doi.org/10.1023/A:1010174515133
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DOI: https://doi.org/10.1023/A:1010174515133