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Synthesis and Thermal Analysis of 2,2′-bipyridine Divalent Transition Metal Hexachloroplumbates

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Abstract

Several complex salts of the general formula [M(II) (bipy)x(H2O)y]PbCl6 (where x=2–3, y=0–2 and M=Mn(II), Fe(II), Ni(II), Co(II), Cu(II), Zn(II), Cd(II) and Hg(II)) were synthesized and investigated by DTA, TG and DTG. Some of the decomposition products were identified by IR spectroscopy and other methods. The compounds decompose with the liberation of water (in the case of hydrates), chlorine (sometimes causing chlorination of organic fragments), organic molecules (sometimes chlorinated) and sometimes hydrogen chloride. The residues comprise metal(II) chlorides and PbCl2.

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References

  1. J. Szychliński, Wiad. Chem., 40 (1966) 495.

    Google Scholar 

  2. J. Błazejowski, J. Szychliński and E. Kowalewska, Thermochim. Acta, 108 (1986) 239.

    Article  Google Scholar 

  3. J. Błazejowski, J. Szychliński and K. Windorpska, Thermochim. Acta, 46 (1981) 147.

    Article  Google Scholar 

  4. I. Guillaume, Bull. Soc. Chim. France, (1960) 494.

  5. J. Szychliński, Zesz. Nauk. Mat., Fiz., Chem., Wyzsza Szk. Pedagog. Gdansku, 7 (1967) 173.

    Google Scholar 

  6. A. F. Kapustinskii, Q. Rev. Chem. Soc. (London), 10 (1956) 283.

    Article  CAS  Google Scholar 

  7. K. B. Yatsimirskii, Zh. Neorg. Khim., 6 (1961) 518.

    CAS  Google Scholar 

  8. L. Gruzdiewa, J. Rak and J. Błazejowski, J. Alloys Compd., 210 (1994) 63.

    Article  CAS  Google Scholar 

  9. J. Rulewski, J. Rak and J. Błazejowski, Hung. Chim. Acta, 131 (1994) 639.

    CAS  Google Scholar 

  10. H. Vu Thanh, L. Gruzdiewa, J. Rak and J. Błazejowski, J. Alloys Compd., 224 (1995) 1.

    Article  Google Scholar 

  11. J. Szychliński, J. Lubkowski, J. Błazejowski and A. Bujewski, J. Thermal Anal, 32 (1987) 1769.

    Article  Google Scholar 

  12. J. Błazejowski and J. Szychliński, Thermochim. Acta, 35 (1980) 211.

    Article  Google Scholar 

  13. T. Janiak and J. Błazejowski, Thermochim. Acta, 157 (1990) 137.

    Article  CAS  Google Scholar 

Download references

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Authors and Affiliations

  1. Department of Chemistry, University of Gdańsk, J. Sobieskiego 18, 80-952, Gdańsk, Poland

    M. Kabir & J. Szychliński

Authors
  1. M. Kabir
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  2. J. Szychliński
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Kabir, M., Szychliński, J. Synthesis and Thermal Analysis of 2,2′-bipyridine Divalent Transition Metal Hexachloroplumbates. Journal of Thermal Analysis and Calorimetry 54, 125–131 (1998). https://doi.org/10.1023/A:1010168919251

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