Abstract
In this work some calorimetric measurements were also carried out on the electrorefining silver by using different current densities with a Calvet type microcalorimeter at room temperature. The ratio (R) of the measured heat (
m) to the input electric energy (
in) and the excess heat (
ex), i.e., difference between
m and
in during the electrorefining process, were discussed in terms of general thermodynamics. It was found that the R and
ex for silver were related with the current density or cell voltage employed in the experiment. The results obtained here also indicate that the heat generation under different conditions, such as different currents or voltages may be caused partially by the irreversibility of the process or by some unknown processes.
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Z. L. Zhang, F. M. Liu, M. H. Zhong, Z. Z. Wang, F. P. Zhong and F. Wu, J. Thermal Anal., 50 (1997) 1.
M. Fleischmann, S. Pons and M. Warkins, J. Electroanal. Chem., 261 (1989) 301.
Z. L. Zhang and S. Y. Liu, Thermodynamic theory of cold nuclear fusion; a) Frontiers of cold fusion, (Frontiers Science Series) No. 4, ISSN 0915–8520, Universal Academy Press, Inc. 1993; b) Progress in physics chemistry mechanics, 3 (1992) 185.
P. A. Rock, Chemical Thermodynamics, University Science Books, Mill Valley, CA 94941, 1983, p. 305.
Z. Zhang, X. Sun, W. Zhou, L. Zhang, B. Li, M. Wang, B. Yan and F. Tan, J. Thermal Anal., 45 (1995) 99.
Z. Zhang, B. Yan, M. Wang and F. Tan, 5th national conference on solution chemistry, thermodynamics, thermochemistry and thermal analysis, (Chengdu, China, 1990–10), Abstracts p. 253.
J. O'M. Bockris and A. K. N. Reddy, Modern Electrochemistry, Plenum Press, New York 1970, Vol. 2, Chaps 8 and 9.
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Zhang, Z.L., Zhong, M.H., Liu, J. et al. Thermokinetic Studies of the Process for Electrorefining Silver. Journal of Thermal Analysis and Calorimetry 58, 421–433 (1999). https://doi.org/10.1023/A:1010167624684
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DOI: https://doi.org/10.1023/A:1010167624684