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The Studies of the Heterogeneous Properties of Solid Surfaces by Means of the Derivatograph Q-1500 D

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Abstract

A simple method has been adopted to obtain an important information on the heterogeneous properties of materials studied, adsorbed liquid films and liquid-solid interactions. The method utilizes Q-TG mass loss and the first derivative Q-DTG mass loss curves with respect to temperature and time obtained during programmed liquid thermodesorption in quasi-isothermal conditions. The values of the adsorption capacity, total porosity of material, the value of active centers, desorption energy distribution and mesopore-size distribution functions obtained by this method are in good agreement with those estimated on the basis of independent methods. The theoretical and experimental results provided novel and unique data on the heterogeneity of solid surfaces, properties of liquid adsorbed films and thermal stability of the liquid/solid interfaces.

This paper presents the more important results obtained so far in the studies the liquid/solid systems by means of the Paulik's classical and quasi-isothermal techniques.

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Authors and Affiliations

  1. Department of Physicochemistry of Solid Surface, Institute of Physical Chemistry, Faculty of Chemistry, Maria Curie-Skłodowska University, M. Curie-Skłodowska Sq. 3, 20-031, Lublin, Poland

    P. Staszczuk

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  1. P. Staszczuk
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Staszczuk, P. The Studies of the Heterogeneous Properties of Solid Surfaces by Means of the Derivatograph Q-1500 D. Journal of Thermal Analysis and Calorimetry 53, 597–616 (1998). https://doi.org/10.1023/A:1010166131014

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