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Thermal Studies of New Cu(I) and Ag(I) Complexes with Bipyridine Isomers

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Abstract

The complexes of the general formula MLSCN (M=Cu(I), Ag(I), L=2,2′-bipyridine=2-bipy, 4,4′-bipyridine=4-bipy or 2,4′-bipyridine=2,4′bipy) have been prepared and their IR spectra examined. The nature of metal-ligand coordination is discussed. Thermal decomposition in air of these complexes occurred in several successive endothermic and exothermic processes and the residue was Cu2O and Ag, respectively.

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Authors and Affiliations

  1. Institute of General and Ecological Chemistry, Technical University, 90-924, Łódź, Poland

    D. Czakis-Sulikowska, J. Kałużna & J. Radwańska-Doczekalska

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  1. D. Czakis-Sulikowska
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  2. J. Kałużna
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  3. J. Radwańska-Doczekalska
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Czakis-Sulikowska, D., Kałużna, J. & Radwańska-Doczekalska, J. Thermal Studies of New Cu(I) and Ag(I) Complexes with Bipyridine Isomers. Journal of Thermal Analysis and Calorimetry 54, 103–113 (1998). https://doi.org/10.1023/A:1010164818342

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  • DOI: https://doi.org/10.1023/A:1010164818342

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