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Effect of the Drawing Process on the Thermal Stability of Gelatine-polyacrylonitrile Graft Copolymer Fibres

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Abstract

The thermal stability of gelatine-polyacrylonitrile graft copolymers fibres obtained under various conditions of deformation has been studied. The thermal properties of examined fibres depend on the synthetic component of the fibre forming material – polyacrylonitrile which appears in the form of grafted PAN chains and PAN homopolymer. It was stated that the highest thermal stability have those fibres which formation process included two stages of drawing with the use of deformation close to the maximal values, with the value of the total draw ratio amounting to 691%. It should be supposed that with such a drawing process, already in its first stage, are created advantageous conditions for the formation of paracrystalline regions to a larger extent and their orientation along the fibre axis.

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Authors and Affiliations

  1. Institute of Polymers, Technical University of Łódź, Łódź, Poland

    G. Janowska

  2. Institute of Man-Made Fibres, Technical University of Łódź, Łódź, Poland

    T. Mikołajczyk

Authors
  1. G. Janowska
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  2. T. Mikołajczyk
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Janowska, G., Mikołajczyk, T. Effect of the Drawing Process on the Thermal Stability of Gelatine-polyacrylonitrile Graft Copolymer Fibres. Journal of Thermal Analysis and Calorimetry 63, 815–822 (2001). https://doi.org/10.1023/A:1010156508023

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  • DOI: https://doi.org/10.1023/A:1010156508023

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