Abstract
Molar excess enthalpies H m E have been determined over the whole composition range for mixtures of benzene, methanol, ethanol, 1-propanol, 2-propanol and 1-butanol with quinoline at 298.15 K using a Thermometric flow calorimeter. The results reflect a strong H-bond association between an alkanol and quinoline which decreases with increasing length of the alkanol chain. The small H m E for (benzene+quinoline) reflects the similarity of the two molecules.
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Letcher, T.M., Deenadayalu, N. Excess Molar Enthalpies and Excess Molar Volumes of Binary Mixtures of Benzene and Alkanols with Quinoline. Journal of Thermal Analysis and Calorimetry 60, 857–860 (2000). https://doi.org/10.1023/A:1010155607684
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DOI: https://doi.org/10.1023/A:1010155607684