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Thermochemical Investigation of Some Selected Solvates of Calix[4]resorcinarene

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Abstract

Lipophilic calix[4]resorcinarene derived from lauryl aldehyde forms stable crystalline solvates with a range of organic solvents: acetone, 1,4-dioxane, methylethylvketone, dimethylformamide, dimethylacetamide, N-methylpyrrolidinone, butyronitrile, methanol, 1,2-dimethoxybenzene and acetonitrile. The composition and thermal stability of these solvates was followed by thermogravimetric method, indicating a stoichiometry ranging from 1 to 3 (calixresorcinarene/solvent). The activation energy was evaluated for the selected solvates. Molecular modelling, using Hyperchem 5.0 software, was applied to the selected solvates.

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Authors and Affiliations

  1. Institute of Physical Chemistry, Polish Academy of Sciences, Kasprzaka 44/52, 01224, Warsaw, Poland

    O. Pietraszkiewicz, E. Utzig, W. Zielenkiewicz & M. Pietraszkiewicz

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  1. O. Pietraszkiewicz
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  2. E. Utzig
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  3. W. Zielenkiewicz
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  4. M. Pietraszkiewicz
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Pietraszkiewicz, O., Utzig, E., Zielenkiewicz, W. et al. Thermochemical Investigation of Some Selected Solvates of Calix[4]resorcinarene. Journal of Thermal Analysis and Calorimetry 54, 249–255 (1998). https://doi.org/10.1023/A:1010153927428

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  • DOI: https://doi.org/10.1023/A:1010153927428

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