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Synthesis, Characterization and Thermal Decomposition of M1[M2(C2O4)2]xH2O (x=5 for M1=Co and x=4 for M1=Cd; M2=Ni)

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Abstract

Cobalt bis(oxalato)nickelate pentahydrate, Co[Ni(C2O4)2]5H2O and cadmium bis(oxalato)nickelate tetrahydrate, Cd[Ni(C2O4)2]4H2O have been synthesized and characterized by elemental analysis, reflectance and IR spectral studies. Thermal decomposition studies (TG, DTG and DTA ) in air showed that both the compound of cobalt and cadmium produced the oxide, MNiOx (x=3 for M=Co; x=2 for M=Cd ) at 325 and 360°C respectively. DSC studies in nitrogen attributed only the mixture of both the metal at the end.

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Authors and Affiliations

  1. Department of Chemistry, North Eastern Regional Institute of Science and Technology, Nirjuli, 791109, Arunachal Pradesh, India

    N. Deb

  2. Regional Research Laboratory, Jorhat, 785006, Assam, India

    S. D. Baruah

  3. Department of Chemistry, Dibrugarh University, Dibrugarh, 786004, Assam, India

    N. N. Dass

Authors
  1. N. Deb
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  2. S. D. Baruah
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  3. N. N. Dass
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Deb, N., Baruah, S.D. & Dass, N.N. Synthesis, Characterization and Thermal Decomposition of M1[M2(C2O4)2]xH2O (x=5 for M1=Co and x=4 for M1=Cd; M2=Ni). Journal of Thermal Analysis and Calorimetry 59, 791–797 (2000). https://doi.org/10.1023/A:1010153720786

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  • DOI: https://doi.org/10.1023/A:1010153720786

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