Abstract
The paper deals with the possible application of various methods to follow the course of reaction between zinc oxide and Fe(III) oxide with respect to various kinds of Fe(III) oxides used (Fe(III) pigments - red, yellow and black). Differential thermal analysis and chemical analysis can be recommended as the most suitable methods for following reactions leading to spinel formation. The possibilities of determining the activation energy of the studied processes are discussed. When Fe(III) red pigment is used as a reactant and therefore no reaction occurs except spinel formation, conductometric thermal analysis was found to be suitable and more sensitive for the evaluation of differences in reactivities.
It has also been observed that the kind of Fe(III) pigment, due to its individual reactivity significantly affects the colouring properties of the final product (e.g., of the ceramic stain).
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References
W. Büchner and R. Schliebs, Industrielle Anorganische Chemie, 2. Auflage, VHC Verlagsgesellschaft GmbH, Weinhcim, 1986, p. 400.
Z. Šolc and M. Trojan, Sklář a keramik, 39 (1989) 16.
A. Kalendová, J. Šňupárek and P. Kalenda, Dyes and Pigments, 30 (1996) 129.
A. Kalendová and P. Kalenda, Polymers Paint Colour Journal, 184 (1994) 570.
F. Paulik, Special Trends in Thermal Analysis, Wiley and Sons, Chichester 1995, p. 140.
J. F. Duncan and D. J. Stewart, J. Trans. Far. Soc., 63 (1967) 1031.
G. A. Kolta, S. Z. El-Tawil and A. A. Ibrahim, Thermochim. Acta, 36 (1980) 359.
W. P. Kingery, Kinetics of High Temperature Processes, Wiley and Sons, Inc., Massachusetts, 1959, p. 243.
R. Furuichi, S. Nakamo, S. Shimada and T. Ishii, Solid States Ionics, 63–65 (1993) 195.
J. Šubrt and J. Tláskal, Solid States Ionics, 63–65 (1993) 110.
M. Ueda, S. Shimada and M. Inagaki, Solid States Ionics, 63–65 (1993) 154.
K. Meyer, Fiziko-Chimičeskaja Kristalografia, Metalurgia, Moskva, 1972.
Z. Šolc, M. Trojan and M. Pokorny, Silikáty, 29 (1985) 351.
V. Balek, Silikáty, 26 (1984) 147.
Z. Šolc, O. Pavliček, M. Trojan and Z. Šmejkal, Thermochim. Acta, 190 (1991) 43.
J. Guilissen and P. J. Van Ryselberghe, Trans. Elektrochem. Soc., 59 (1931) 95.
J. Málek and V. Smrčka, Thermochim. Acta, 186 (1991) 153.
S. F. Hulbert, J. Brit. Ceram. Soc., 1 (1970) 11.
J. Málek, Thermochim. Acta, 200 (1992) 257.
A Kalendová, J. Šňupárck and P. Kalenda, ACS — PMSE Symposium on ‘Corrosion Control by Coatings’, New Orleans 1996.
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Konvička, T., Šolc, Z., Mošner, P. et al. Comparison of Various Analytical Methods in the Study of the Reaction Between Zinc Oxide and Fe(III) Oxide. Journal of Thermal Analysis and Calorimetry 54, 845–853 (1998). https://doi.org/10.1023/A:1010152206146
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DOI: https://doi.org/10.1023/A:1010152206146