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The Enthalpy of Solution in Water of Histidine Complexes of Re Nitrates

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Abstract

The enthalpies of solution in water of RE(His)(NO3)3⋅H2O (RE=La—Nd, Sm—Lu, Y) were measured calorimetrically at 298.15 K, and the standard enthalpies of formation of RE(His) 3+aq (RE=La—Nd, Sm—Lu, Y) were calculated. The plot of the enthalpies of solution vs. the atomic numbers of the elements in the lanthanide series exhibits the ‘tetrad effect’.

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References

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Authors and Affiliations

  1. Department of Chemistry, Northwest University, Xian, 710069, Shaanxi, P. R. China

    M. Ji, J. Liu, S. Gao & Q. Shi

  2. Xian Modern Chemistry Research Institute, Xian, 710065, Shaanxi, P. R. China

    B. Kang & R. Hu

Authors
  1. M. Ji
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  2. J. Liu
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  3. S. Gao
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  4. B. Kang
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  5. R. Hu
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  6. Q. Shi
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Ji, M., Liu, J., Gao, S. et al. The Enthalpy of Solution in Water of Histidine Complexes of Re Nitrates. Journal of Thermal Analysis and Calorimetry 58, 339–345 (1999). https://doi.org/10.1023/A:1010147020141

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  • DOI: https://doi.org/10.1023/A:1010147020141

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