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Molecular Modelling of Thermodynamic and Related Properties of Mixtures

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Abstract

The results of recent developments on modelling of supramolecular ordering and physicochemical properties of molecular mixtures have been reviewed. The main attention is paid to the unified approach based on a generalized quasichemical model for a set of thermodynamic, dielectric and optical properties of mixtures, self-organized by specific bonding. Interrelations between thermodynamic, as well as dielectric, and optical properties of liquid mixtures, reflecting different molecular parameters, and the characteristics of quasichemical processes are presented. Applications for thermodynamic functions of mixing, permittivity, coefficients Rayleigh light scattering in molecular mixtures are considered. Data on thermodynamics of aggregation in mixtures have been obtained.

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References

  1. W. E. Acree, Jr., Thermodynamic Properties of Non-electrolyte Solutions, Academic Press, Orlando 1984.

    Google Scholar 

  2. K. N. March and F. Kohler, J. Mol. Liq., 30 (1985) 13.

    Article  Google Scholar 

  3. V. A. Durov, Zh. Fiz. Khim., 67 (1993) 290.

    CAS  Google Scholar 

  4. V. A. Durov, J. Mol. Liq., 78 (1998) 51.

    Article  CAS  Google Scholar 

  5. I. Prigogine and P. Defay, Chemical Thermodynamics, Longmans Green, London 1954.

    Google Scholar 

  6. V. A. Durov, Zh. Fiz. Khim., 65 (1991) 1766.

    CAS  Google Scholar 

  7. V. A. Durov and I. Yu. Shilov, Zh. Fiz. Khim., 68 (1994) 184.

    CAS  Google Scholar 

  8. V. A. Durov, Zh. Fiz. Khim., 55 (1981) 2833; 56 (1982) 1950.

    Google Scholar 

  9. V. A. Durov, Zh. Fiz. Khim., 63 (1989) 1587.

    Google Scholar 

  10. V. A. Durov, Chemical Thermodynamics. A 'Chemistry for the 21st Century'. (Ed. T. Letcher), Blackwell Science, London 1999, p. 327.

    Google Scholar 

  11. V. A. Durov, Zh. Fiz. Khim., 55 (1981) 882.

    CAS  Google Scholar 

  12. V. A. Durov, Quasichemical Models in Physical Chemistry of Liquid Nonelectrolytes (in Russian), Dr. Habil. Sc. Dissertation, Lomonosov Moscow State University, Moscow 1989.

    Google Scholar 

  13. V. A. Durov and E. P. Ageev, Thermodynamic Theory of Non-electrolyte Solutions (monograph in Russian), Moscow State University Press, Moscow 1987.

    Google Scholar 

  14. V. A. Durov, Zh. Fiz. Khim., 63 (1989) 1750, 1759, 2033.

    CAS  Google Scholar 

  15. H. Frohlich, Theory of Dielectrics, Clarendon Press, Oxford 1958.

    Google Scholar 

  16. W. H. Flygare, Chem. Soc. Rev., 6 (1977) 109.

    Article  CAS  Google Scholar 

  17. V. A. Durov, Vestn. Mosk. Univ., Ser. Khim., 28 (1987) 54.

    CAS  Google Scholar 

  18. V. A. Durov, V. I. Zhuravlev and Th. A. Romm, Zh. Fiz. Khim., 59 (1985) 96, 102.

    CAS  Google Scholar 

  19. V. A. Durov and I. Yu. Shilov, J. Chem. Soc., Faraday Trans., 92 (1996) 3559.

    Article  CAS  Google Scholar 

  20. V. A. Durov and I. Yu. Shilov, Zh. Fiz. Khim., 70 (1996) 818.

    CAS  Google Scholar 

  21. V. A. Durov and I. Yu. Shilov, Zh. Fiz. Khim., 70 (1996) 1224.

    CAS  Google Scholar 

  22. V. A. Durov and I. Yu. Shilov, Zh. Fiz. Khim., 69 (1995) 1745.

    CAS  Google Scholar 

  23. V. A. Durov and I. Yu. Shilov, Zh. Fiz. Khim., 70 (1996) 2180.

    CAS  Google Scholar 

  24. V. A. Durov and I. Yu. Shilov, Zh. Fiz. Khim., 71 (1997) 412.

    Google Scholar 

  25. V. A. Durov and T. M. Usacheva, Zh. Fiz. Khim., 56 (1982) 648.

    CAS  Google Scholar 

  26. V. A. Durov, B. Dj. Bursulaya and A. Artykov, Zh. Fiz. Khim., 63 (1989) 3192.

    CAS  Google Scholar 

  27. I. Yu. Shilov, B. M. Rode and V. A. Durov, Chem. Phys., 241 (1999) 75.

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Department of Physical Chemistry, Faculty of Chemistry, Lomonosov Moscow State University, Moscow, RU-119899, Russia

    V. A. Durov

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  1. V. A. Durov
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Durov, V.A. Molecular Modelling of Thermodynamic and Related Properties of Mixtures. Journal of Thermal Analysis and Calorimetry 62, 15–27 (2000). https://doi.org/10.1023/A:1010146308218

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