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Behaviour of Hydrotalcite and Its Fe (CN)64- Pillared Derivative on Heat Treatment

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Abstract

Mg-Al L(ayered) D(ouble) H(ydroxide) was prepared and its thermal behaviour was characterized by thermoanalytical methods (TG, DTG, DTA), 27Al M(agic) A(ngle) S(pinning) NMR spectroscopy, X-ray diffractometry (XRD) and S(canning) E(lectron) M(icroscopy). Heat treatment destroyed the layered structure, which could only be partially reconstituted by rehydration. On calcination mixed oxide with the predominance of basic sites were formed. Pillaring the LDH with Fe(CN)6 4- anions was also performed. The material was characterized by XRD and BET measurements. Heat stability of the pillared substance was investigated, too. Pillaring proved to be successful, however, decreased heat resistance was found in the intercalated material relative to the guest LDH.

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Authors and Affiliations

  1. Applied Chemistry Department, József Attila University, Rerrich B. tér 1, Szeged

    A. Béres, Á. Fudala & I. Kiricsi

  2. Department of Organic Chemistry, József Attila University, Dóm tér 8, Szeged, H-6720, Hungary

    I. Pálinkó

  3. Molecular Recognition Laboratory, National Institute of Materials and Chemical Research, 1-1 Higashi, Tsukuba, Ibaraki, Japan

    Y. Kiyozumi & F. Mizukami

  4. Unité de RMN, Facultés, Universitaires Notre-Dame de la Paix, 61 rue Bruxelles, Namur, B-5000, Belgique

    J. B. Nagy

Authors
  1. A. Béres
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  2. I. Pálinkó
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  3. Á. Fudala
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  4. I. Kiricsi
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  5. Y. Kiyozumi
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  6. F. Mizukami
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  7. J. B. Nagy
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Béres, A., Pálinkó, I., Fudala, Á. et al. Behaviour of Hydrotalcite and Its Fe (CN)64- Pillared Derivative on Heat Treatment. Journal of Thermal Analysis and Calorimetry 56, 311–316 (1999). https://doi.org/10.1023/A:1010138314956

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  • DOI: https://doi.org/10.1023/A:1010138314956

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