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Heat Capacities of Hydroxy and Aminoderivatives of Benzene

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Abstract

Heat capacities in the liquid phase C l of methylbenzeneamines and heat capacities in the solid phase C s of benzenediols and of 4-methylbenzeneamine were measured by commercial Setaram heat conduction and power compensated calorimeters. Results obtained cover the following temperature range (depending on the compound and state of aggregation): 2-methylbenzeneamine 313 to 371 K, 3-methylbenzeneamine 263 to 371 K, 4-methylbenzeneamine 133 to 353 K, 1,2-benzenediol 153 to 353 K, 1,3-benzenediol 173 to 353 K, 1,4-benzenediol 133 to 403 K. The heat capacity data obtained in this work were merged with experimental data from literature, critically assessed and sets of recommended data were developed by correlating selected data as a function of temperature.

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Authors and Affiliations

  1. Department of Physical Chemistry, Institute of Chemical Technology, Technická 5, 166 28, Prague 6, Czech Republic

    M. Čenský, M. Lipovská & V. Růžička

  2. Institute of Physical Chemistry, Faculty of Chemistry and Physics, Technical University – Bergakademie Freiberg, Leipziger Strasse 29, D-09596, Freiberg/Sachsen, Germany

    H.-G. Schmidt & G. Wolf

Authors
  1. M. Čenský
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  2. M. Lipovská
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  3. H.-G. Schmidt
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  4. V. Růžička
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  5. G. Wolf
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Čenský, M., Lipovská, M., Schmidt, HG. et al. Heat Capacities of Hydroxy and Aminoderivatives of Benzene. Journal of Thermal Analysis and Calorimetry 63, 879–899 (2001). https://doi.org/10.1023/A:1010125128496

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