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Thermodynamics of formation of Triiodide Complexes and Solvation of Reagents in Alkanolic Solutions of Electrolytes

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Abstract

The aim of this investigation was to study the influence of electrolytes on a reaction of triiodide complex formation. Investigation of the salt effect as concerns the thermodynamics of I −3 formation in methanol, ethanol and n-propanol solutions revealed regularities of the influence of the electrolyte on triiodide complex formation connected with a multifactorial effect of the ionic medium. The quasichemical model presented was used to calculate parameters reflecting the overall salt effect.

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Authors and Affiliations

  1. Institute of Non-Aqueous Solution Chemistry of Russian Academy of Sciences, Academicheskaya u. 1, Ivanovo, 153045, Russia

    A. V. Vladimirov & A. V. Agafonov

Authors
  1. A. V. Vladimirov
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  2. A. V. Agafonov
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Vladimirov, A.V., Agafonov, A.V. Thermodynamics of formation of Triiodide Complexes and Solvation of Reagents in Alkanolic Solutions of Electrolytes. Journal of Thermal Analysis and Calorimetry 54, 297–303 (1998). https://doi.org/10.1023/A:1010118430154

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  • DOI: https://doi.org/10.1023/A:1010118430154

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