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Inhibited Oxidation of Cumene and Polymerization of Styrene Investigated by Solution Microcalorimetry

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Abstract

The application of solution microcalorimetry was demonstrated on two model examples – inhibited oxidation of cumene and radical polymerization of styrene.

From the experimental dependences of the rate of heat release on time, the rate constants k 7 of the interaction of an inhibitor with radicals of substrate (RO .2 or R.) in oxidation or in polymerization were determined for the set of inhibitors of N-aryl N-(2-quinone) amine series. It was shown that these compounds are weak inhibitors of oxidation of cumene and rather efficient inhibitor of polymerization of styrene.

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Authors and Affiliations

  1. Institute of Crude Oil Chemistry, Academy of Sciences, 634 36, Tomsk, Russia

    A. Velikov

  2. Polymer Institute, Slovak Academy of Sciences, 842 36, Bratislava, Slovak Republic

    L. Matisová-Rychlá, R. Broska & J. Rychly

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  1. A. Velikov
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  2. L. Matisová-Rychlá
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  3. R. Broska
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  4. J. Rychly
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Velikov, A., Matisová-Rychlá, L., Broska, R. et al. Inhibited Oxidation of Cumene and Polymerization of Styrene Investigated by Solution Microcalorimetry. Journal of Thermal Analysis and Calorimetry 57, 473–486 (1999). https://doi.org/10.1023/A:1010116024873

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