Abstract
The phase behavior of several polycarbonate homopolymers and copolymers blended with PVC and chlorinated PVCs (CPVCs) has been investigated. Tetrachlorobisphenol-A polycarbonate (TCPC) is miscible in all proportions with PVC and CPVCs containing up to70.2 wt% chlorine. CPVCs having chlorine contents greater than 70.2% (by weight) are immiscible with TCPC. Tetrabromobisphenol-A polycarbonate (TBPC) exhibits phase mixing with PVC and CPVCs; however, the high Tg of this polycarbonate (260°C) prevents adequate investigation of equilibrium phase behavior. Bisphenol-A polycarbonate (BPC), tetramethylbisphenol-A polycarbonate (TMPC), and hexafluorobisphenol-A polycarbonate (HFPC) form two-phase mixtures with the vinyl polymers. Microstructural differences in the CPVCs due to chlorination method (solution chlorination vs. slurry chlorination) have no effect on the miscibility results. Miscibility was observed in several copolycarbonate/CPVC blends and was found to be dependent on copolymer composition. Using a binary interaction, mean-field theory, segmental interaction parameters were estimated for repeat unit interactions. Based on the estimated interaction parameters, miscibility in these blends is primarily the result of intramolecular repulsive effects, rather than strong intermolecular attractive forces.
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S. E. Elghani, W. Fischer, M. Koehler, J. Lindner and R. Prinz, US Patent 3, 882, 192 (Bayer), May 6, 1977.
F. Mietzsch, D. Hardt, V. Serini, H. Bartl and H. Vernaleken, US Patent 4, 005, 037 (Bayer), Jan. 25, 1977.
D. Hardt, V. Serini, H. Vernaleken and H. Braese, US Patent 4, 105, 711 (Bayer), Aug. 8, 1978.
H. Braese, W. Fischer, D. Hardt, R. Prinz and V. Serine, US Patent 4, 239, 861 (Bayer), Dec. 16, 1980.
J. M. H. Heuschen, J. Bussink and W. L. Sederel, US Patent 4, 504, 623 (General Electric), March 12, 1985.
J. M. H. Heuschen, J. Bussink and W. L. Sederel, US Patent 4, 504, 624 (General Electric), March 12, 1985.
Biing-Lin Lee, US Patent 4, 680, 343 (B. F. Goodrich), July 14, 1987.
L. M. Robeson, J. E. Harris, J. H. Kawakami and L. M. Maresca, US Patent 4, 698, 390 (Amoco), Oct. 6, 1987.
N. Fujii and Y. Shibazaki, JP Patent 01104645 (Sekisui), 1989.
N. Fujii and Y. Shibazaki, JP Patent 01104644 (Sekisui), 1989.
E. J. Termine, J. Vinyl Technol., 12 (4) (1990) 204.
D. Braun, B. Bohringer and J. Herth, Makromol. Chem., Macromol. Symp., 29 (1989) 227.
E. M. Woo, J. W. Barlow and D. R. Paul, J. Appl. Polym. Sci., 30 (1985) 4243.
J. M. G. Cowie, E. M. Elexpuru and I. J. McEwen, J. Polym. Sci., B, Polym. Phys., 29 (1991) 407.
Y. F. Chong and S. H. Goh, Polymer, 33 (1) (1992) 127.
T. S. Ellis, Polym. Eng. Sci., 30 (17) (1990) 998.
W. Huh and F. E. Karasz, Macromolecules, 25 (1992) 1057.
G. ten Brinke, F. E. Karasz and W. J. MacKnight, Macromolecules, 16 (1983) 1827.
R. P. Kambour, J. T. Bendler and R. C. Bopp, Macromolecules, 16 (1983) 753.
D. R. Paul and J. W. Barlow, Polymer, 25 (1984) 487.
P. J. Flory, J. Chem. Phys., 9 (1941) 660.
M. L. Huggins, J. Chem. Phys., 9 (1941) 440.
T. Shiomi, M. Suzuki, M. Tohyama and K. Imai, Macromolecules, 22 (9) (1989) 3578.
R. A. Komoroski, R. G. Parker and J. P. Shockcor, Macromolecules, 18 (6) (1985) 1257.
J. R. Fried, F. E. Karasz and W. J. MacKnight, Macromolecules, 11 (1) (1978) 150.
T. G. Fox, Bull. Am. Phys. Soc., 1 (1956) 123.
P. R. Couchman, Macromolecules, 11 (6) (1978) 1156.
C. K. Kim and D. R. Paul, Polymer, 33 (23) (1992) 4929.
T. Shiomi, F. E. Karasz, W. J. MacKnight, Macromolecules, 19 (8) (1986) 2274.
S. Krause, in Polymer Blends; D. R. Paul, S. Newman, Eds.; Academic Press, New York 1978.
J. T. Neill, Ph. D. Dissertation. University of Massachusetts Amherst, May 1994.
D. W. Van Krevelen, Properties of Polymers. 3rd Ed. Elsevier, New York 1990. Chapter 3.
R. Vukovic, private communication.
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Neill, J.T., Karasz, F.E. Miscibility of Some Polycarbonates with Polyvinyl Chloride and Chlorinated Polyvinyl Chloride. Journal of Thermal Analysis and Calorimetry 59, 33–58 (2000). https://doi.org/10.1023/A:1010115408506
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DOI: https://doi.org/10.1023/A:1010115408506