Skip to main content
SpringerLink
Log in

Excess Enthalpies of Binary Mixtures of Formamide with Secondary Amides

  • Published:
Journal of Thermal Analysis and Calorimetry Aims and scope Submit manuscript

Abstract

The excess molar enthalpies HE of binary mixtures of formamide with N-methylformamide, N-ethylformamide, N-methylacetamide, N-ethylacetamide and N-methylpropion-amide have been measured as functions of the mole fraction at 308.15 K, using an isoperibol rotating calorimeter. The experimental values of HE are negative for all mixtures over the whole composition range. Intermolecular interactions in these mixtures are discussed through comparison of the results with those for corresponding binary mixtures of water.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Yu. M. Kessler and A. L. Zaitsev, Solvophobic Effects, Elis Horwood, Chichester 1994.

  2. A. M. Zaichikov and G. A. Krestov, Russ. J. Phys. Chem., 69 (1995) 353.

    Google Scholar 

  3. A. M. Zaichikov and Yu. G. Bushuev, Russ. J. Phys. Chem., 69 (1995) 1766.

    Google Scholar 

  4. A. M. Zaichikov, Yu. G. Bushuev and G. A. Krestov, J. Thermal Anal., 45 (1995) 687.

    CAS  Google Scholar 

  5. A. M. Zaichikov and O. E. Golubinskii, Russ. J. Phys. Chem., 70 (1996) 1971.

    Google Scholar 

  6. A. M. Zaichikov and O. E. Golubinskii, Russ. J. Phys. Chem., 70 (1996) 1090.

    Google Scholar 

  7. A. M. Zaichikov, Russ. J. Gen. Chem., in press.

  8. H. Ohtaki, S. Itoh and B. M. Rode, Bull. Chem. Soc. Jpn., 59 (1986) 271.

    Article  CAS  Google Scholar 

  9. W. L. Jorgensen and C. J. Swenson, J. Am. Chem. Soc., 107 (1985) 569.

    Article  CAS  Google Scholar 

  10. A. M. Zaichikov, O. E. Golubinskii and N. I. Zheleznyak, Izv. Vuzov. Khim. Khim. Technol., 33 (1990) 124.

    Google Scholar 

  11. A. M. Zaichikov, E. A. Nogovitsyn, N. I. Zheleznyak and G. A. Krestov, Russ. J. Phys. Chem., 62 (1988) 1630.

    Google Scholar 

  12. E. Z. Li, L. P. Zaichenko, A. A. Abramson, V. A. Proskuryakov and A. A. Slavin, Zh. Obshch. Khim., 54 (1984) 254.

    CAS  Google Scholar 

  13. K. Pralat, J. Jadzyn and S. Balanicka, J. Phys. Chem., 87 (1983) 1385.

    Article  CAS  Google Scholar 

  14. M. Lindheimer, G. Etienne and B. Brun, J. Chim. Phys., 5 (1972) 829.

    Google Scholar 

  15. A. Burneau, J. Mol. Liq., 46 (1990) 99.

    Article  CAS  Google Scholar 

  16. J. N. Spenser, S. K. Berger, C. R. Powell, B. D. Henning, G. G. Furman, W. M. Loffredo, E. M. Rydberg, R. A. Neubert, C. E. Shoop and D. N. Blanch, J. Phys. Chem., 85 (1981) 1236.

    Article  Google Scholar 

  17. M. Bloemendal, K. Booij and G. Somsen, J. Chem. Soc. Faraday Trans., P. 1, 81 (1985) 1015.

    Article  CAS  Google Scholar 

  18. A. Zielenkiewicz, Thermochim. Acta, 79 (1984) 371.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Inorganic Chemistry, Ivanovo State Academy of Chemical Technology, pr. Engelsa 7, 153460, Ivanovo, Russia

    A. M. Zaichikov

Authors
  1. A. M. Zaichikov
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Zaichikov, A.M. Excess Enthalpies of Binary Mixtures of Formamide with Secondary Amides. Journal of Thermal Analysis and Calorimetry 54, 279–284 (1998). https://doi.org/10.1023/A:1010114229246

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/A:1010114229246

Search

Navigation