Skip to main content
SpringerLink
Log in

Phase Transitions in Crystalline [M(H2O)6](ClO4)2 (M=Mg, Mn, Fe, Co, Ni, Cu, Zn, Cd and Hg)

  • Published:
Journal of Thermal Analysis and Calorimetry Aims and scope Submit manuscript

Abstract

The results of DSC measurements in the temperature range 140–370 K on nine crystalline compounds of the type [M(H2O)6](ClO4)2, where M=Mg, Mn, Fe, Co, Ni, Cu, Zn, Cd and Hg, are discussed. Anomalies detected in the DSC curves are related to the existence of solid-solid phase transitions and/or to the melting points of these compounds. In consequence of two different hypothetical structural modifications of [Fe(H2O)6](ClO4)2, two DSC curves are obtained. For the compounds with M=Fe, Cd and Hg, new phase transitions have been discovered. The transition temperatures of the other phase transitions are in good agreement with literature data obtained by adiabatic calorimetry. For the compounds with M=Mg, Ni and Cd, DTA measurements were also carried out and the melting points of theses compounds were established.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. C. D. West, Z. Kristall., 91A (1935) 480.

    Google Scholar 

  2. C. D. West, Z. Kristall., 88A (1934) 198.

    Google Scholar 

  3. A. Scqueira, I. Bernal, I. D. Brown and R. Faggiani, Acta Cryst. B, 31 (1975) 1735.

    Article  Google Scholar 

  4. M. Ghosh and S. Ray, Z. Kristall., 145 (1977) 146.

    Article  CAS  Google Scholar 

  5. G. Johansson and M. Sandstroem, Acta Chem. Scand. A, 42 (1987) 113.

    Google Scholar 

  6. G. Johansson and M. Sandstroem, Acta Chem. Scand. A, 32 (1978) 109.

    Article  Google Scholar 

  7. M. Ghosh and S. Ray, Indian J. Phys., 48 (1974) 1149.

    Google Scholar 

  8. M. Ghosh and S. Ray, Z. Kristall., 155 (1981) 129.

    Article  CAS  Google Scholar 

  9. N. V. Mani and S. Ramaseshan, Z. Kristall., 115 (1961) 97.

    Article  CAS  Google Scholar 

  10. J. C. Gallucci and R. E. Gerkin, Acta Cryst. C, 45 (1989) 1279.

    Article  Google Scholar 

  11. M. A. White and M. Falk, J. Chem. Phys., 84 (1986) 3484.

    Article  CAS  Google Scholar 

  12. M. A. White and M. Falk, J. Chem. Phys., 83 (1985) 2467.

    Article  CAS  Google Scholar 

  13. E. Mikuli, A. Migdal-Mikuli, M. Rachwalska and T. Stanek, Physica B, 104 (1981) 326.

    Article  CAS  Google Scholar 

  14. M. P. Sinha, A. Pal and S. K. Roy, J. Phys. C: Solid St. Phys., 9 (1976) 2783.

    Article  CAS  Google Scholar 

  15. M. Rachwalska and T. Stanek, Phys. Stat. Sol. (A), 48 (1978) 297.

    CAS  Google Scholar 

  16. M. Godlewska and M. Rachwalska, J. Thermal Anal., 45 (1995) 1073.

    CAS  Google Scholar 

  17. E. Mikuli, A. Migdal-Mikuli and J. Mayer, Mol. Cryst. Liq. Cryst. C: Mol. Mat., 8 (1997) 273.

    CAS  Google Scholar 

  18. A. Migdal-Mikuli, E. Mikuli and J. Mayer, Mol. Cryst. Liq. Cryst. C: Mol. Mat., 9 (1998) 205.

    CAS  Google Scholar 

  19. A. K. Jain and G. C. Upreti, J. Phys. Chem. Solids, 44 (1983) 549.

    Article  CAS  Google Scholar 

  20. R. Dayal, D. Ramachandra Rao and P. Venkateswarlu, Can. J. Phys., 56 (1978) 1175.

    CAS  Google Scholar 

  21. R. Dayal, D. Ramachandra Rao and P. Venkateswarlu, J. Magn. Res., 36 (1979) 99.

    CAS  Google Scholar 

  22. A. K. Jain and G. C. Upreti, J. Phys. C: Solid. St. Phys., 13 (1980) 5177.

    Article  CAS  Google Scholar 

  23. J. C. Sartorelli, S. Isotani, J. A. Ochi, W. Sano and A. Piccini, Chem. Phys. Letters, 57 (1978) 608.

    Article  CAS  Google Scholar 

  24. A. K. Jain and G. C. Upreti, Solid State Commun., 28 (1978) 571.

    Article  CAS  Google Scholar 

  25. A. K. Jain and G. C. Upreti, J. Phys. Chem. Solids, 43 (1982) 563.

    Article  CAS  Google Scholar 

  26. R. Dayal, D. Ramachandra Rao and P. Venkateswarlu, J. Chem. Phys., 70 (1979) 2487.

    Article  CAS  Google Scholar 

  27. A. K. Jain and G. C. Upreti, Phys. Stat. Sol. (A), 58 (1980) 155.

    CAS  Google Scholar 

  28. I. Svare, B. O. Fimland, K. Otnes, J. A. Janik, J. M. Janik, E. Mikuli and A. Migdał-Mikuli, Physica B, 106 (1981) 195.

    Article  CAS  Google Scholar 

  29. I. Svare and B. O. Fimland, J. Chem. Phys., 74 (1981) 5977.

    Article  CAS  Google Scholar 

  30. B. Borzęcka, S. F. Sagnowski and S. Hodorowiez, Phys. Stat. Sol. (A), 64 (1981) 557.

    Google Scholar 

  31. B. K. Chaudhuri, J. Phys. C: Solid St. Phys., 8 (1975) 1285.

    Article  Google Scholar 

  32. B. K. Chaudhuri, Solid. State. Commun., 16 (1975) 767.

    Article  CAS  Google Scholar 

  33. B. K. Chaudhuri and D. Ghosh, Phys. Stat. Sol. (A), 23 (1974) 649.

    CAS  Google Scholar 

  34. B. K. Chaudhuri, J. Phys. C: Solid St. Phys., 8 (1975) 1285, 1884

    Article  Google Scholar 

  35. B. K. Chaudhuri, J. Phys. C: Solid St. Phys., 7 (1974) 3962.

    Article  CAS  Google Scholar 

  36. I. Dezsi and L. Keszthelyi, Solid St. Commun., 4 (1966) 511.

    Article  CAS  Google Scholar 

  37. J. M. D. Coey, I. Dezsi, P. M. Thomas and P. J. Ousepf, Phys. Letters, 41A (1972) 125.

    Google Scholar 

  38. B. Brunot, Chem. Phys. Letters, 29 (1974) 368.

    Article  CAS  Google Scholar 

  39. J. M. Janik, A. Migdał-Mikuli, E. Mikuli and T. Stanck, Acta Phys. Polon. A, 59 (1981) 599.

    Google Scholar 

  40. M. B. Patel and H. D. Bist. J. Phys. (Paris), Suppl. 12 C6, 42 (1981) 917.

    Google Scholar 

  41. M. B. Patel, S. Patel, D. P. Khandelwal and H. D. Bist, Chem. Phys. Letters, 101 (1983) 93.

    Article  CAS  Google Scholar 

  42. M. B. Patel and H. D. Bist, Solid St. Commun., 48 (1983) 139.

    Article  CAS  Google Scholar 

  43. M. B. Patel and H. D. Bist, J. Chem. Phys., 79 (1983) 4489.

    Article  CAS  Google Scholar 

  44. L. Novakovic, J. Dojcilovic, M. V. Napijalo and M. Lj. Napijalo, Solid St. Commun., 76 (1990) 73.

    Article  CAS  Google Scholar 

  45. L. Novakovic, J. Dojcilovic, M. V. Napijalo and M. Lj. Napijalo, Solid St. Commun., 70 (1989) 1031.

    Article  CAS  Google Scholar 

  46. J. A. Janik, J. M. Janik and T. Stanek, Acta Phys. Polon. A, 59 (1981) 815.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Chemical Physics, Faculty of Chemistry of the Jagiellonian University, Ingardena Street 3, 30-060, Cracow

    E. Mikuli & A. Migdał-Mikuli

  2. H. Niewodniczański Institute of Nuclear Physics, Radzikowskiego Street 152, 31-342, Cracow, Poland

    J. Mayer

Authors
  1. E. Mikuli
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. Migdał-Mikuli
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. J. Mayer
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Mikuli, E., Migdał-Mikuli, A. & Mayer, J. Phase Transitions in Crystalline [M(H2O)6](ClO4)2 (M=Mg, Mn, Fe, Co, Ni, Cu, Zn, Cd and Hg). Journal of Thermal Analysis and Calorimetry 54, 93–102 (1998). https://doi.org/10.1023/A:1010112801504

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/A:1010112801504

Search

Navigation