Abstract
Zirconia samples with different structures (monoclinic, tetragonal or a mixture of the two) was prepared by different methodologies, including a novel procedure involving the precipitation of an oxalate precursor and the formation of pure tetragonal ZrO2.
The different precursors obtained by varying the preparative procedure (ex oxychloride, ex oxalate, and ex gel) were studied by means of differential thermal analysis and thermogravimetric analysis under air and under N2, while the final oxides were characterized by BET, porosimetry and XRD analysis. The surface acid-base properties of the different oxides were assessed via the catalytic decomposition isopropanol. A prevalence of acid sites found for the ex-oxalate ZrO2 seems to justify the different mechanism of chain growth observed in the carbonylation of methanol with CO/H2 mixtures in the presence of Rh.
Similar content being viewed by others
References
S. Somiya, N. Yamamoto and H. Yanagida (Eds), Science and Technology of Zirconia III, Am. Ceram. Soc., (1988), ISBN 0-916094-87-1.
K. Tanabe, Mat. Chem. Phys., 13 (1985) 347.
P. D. L. Mercera, Ph.D. Thesis, University of Twente (1991). ISBN 90.9004189-3.
E. C. Subbarao, in A. H. Heuer and L. W. Hobbs (Eds), Science and Technology of Zirconia, Am. Ceram. Soc., (1981) ISBN 0-916094-42-1.
A. Clearfield, G. P. D. Serrette and A. H. Khazi-Syed, Catal Today, 20 (1994) 295.
S. V. Elinson and K. I. Patrov, Trans. N. Kaner, Analytical Chemistry of Zirconium and Hafnium, Ann. Arvùbor, (1969) ISBN 250 399121.
UK Patent Application GB 2051767A.
B. Aiken, W. P. Hsu and E. Matijevic, J. Mat. Sci., 25 (1990) 1886.
K. Tanabe and T. Yamaguchi, Catal. Today, 20 (1994) 185.
K. Tanabe, Mat. Chem. Phys., 13 (1985) 347.
P. Moles, Appl. Catal., A 87 (1992) N2.
L. Bruce and J. F. Mathews, Appl. Catal., 4 (1982) 353.
P. Turlier, J. A. Dalmon and G. A. Martin, in: Studies in Surface Science and Catalysis, Vol. 11, B. Imelik et al. (Eds), Elseviers, Amsterdam 1982 p. 203.
M.-Y. He and J. G. Ekerdt, J. Catal., 87 (1984) 238.
Y. Sun and P. A. Sermon, J. Chem. Soc. Chem. Commun., (1993) 1242.
A. Gervasini, F. Morazzoni, D. Stumolo, F. Pinna, G. Strukul and L. Zanderighi, J. Chem. Soc. Faraday Trans., I 82 (1986) 1795.
R. Seymansky, H. Chancosset, P. Gullezot and L. Tournayan, J. Catal., 97 (1986) 366.
J. Lecompte, P. Orlans and B. Guilhot, in ‘Calorimétrie et Analyse thermique’, Vol. 14, Association Française de Calorimétrie et d'Analyse Thermique (Eds), Univesité Libre de Bruxelles 14–16 May, 1984, p. 284.
E. Crucean and B. Rand, Transact. J. British Ceram. Soc., 78 (1979) 58.
C. Mazzocchia, R. Anouchinsky, A. Kaddouri, M. Sautel and G. Thomas, J. Thermal Anal., 40 (1993) 1253.
J. Clearfield, J. Inorg. and Nucl. Chem., 11 (1959) 169.
ASTM Powder Diffraction File 17-923, U.S. Bureau of Mines, Albany.
M. Osendi, J. Moya, C. Serna and J. Soria, J. Amer. Ceram. Soc., 68 (1985) 135.
Annual report forwarded to the C.E.E, unpublished results.
E. Tempesti, A. Kiennemann, S. Rapagnà, C. Mazzocchia and L. Giuffrè, Chemistry and Industry, (1991) 548.
C. Mazzocchia, E. Tempesti, P. Gronchi, L. Giuffrè and L. Zanderighi, J. Catal., 111 (1988) 345.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Kaddouri, A., Mazzocchia, C., Tempesti, E. et al. On the Activity of ZrO2 Prepared by Different Methods. Journal of Thermal Analysis and Calorimetry 53, 97–109 (1998). https://doi.org/10.1023/A:1010110024557
Issue Date:
DOI: https://doi.org/10.1023/A:1010110024557