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Investigation of Novel Organometallics by Thermal Spectroscopic Methods

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Abstract

The photolysis of W(CO)6in CH2Cl2 produces (CO)5WCH2Cl2. The high reactivity of (CO)5WCH2Cl2 (1) was exploited to synthesize a vinylidene complexes via the acetylene-vinylidene rearrangement. The addition of a terminal acetylene (H-C≡C-COOCH3) to a solution of (1) produced the η2-acetylene-pentacarbonyltungsten complex (CO)5W(η2-HC≡C-COOCH3) in good yield. The production of the vinylidene complex (CO)5W=C=CH-COOCH3in equilibrium with the acetylene complex in the reaction medium was verified experimentally by reaction with excess imine. The heterocyclic organometallic compound of tungsten obtained was separated and purified and its structure was studied by IR, 1H NMR, 13C NMR and mass spectrometry in comparison with the thermal analysis and elemental analysis data. The final aim of this investigation is the development of a new alternative route to a β-lactame with antibacterial activity.

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References

  1. E. O. Fischer and A. Maasböl, Angew. Chem., 76 (1964) 645, Angew. Chem. Int. Ed. Engl., 3 (1964) 580.

    CAS  Google Scholar 

  2. H. Fischer, K. H. Dötz, P. Hofmann, F. R. Kreiss, U. Schubert and K. Weiss, Transition Metal Carbene Complexes, Verl. Chemie, Weinheim 1983.

    Google Scholar 

  3. F. J. Brown, Prog. Inorg. Chem., 27 (1980) 1.

    CAS  Google Scholar 

  4. H. Fischer, in F. R. Hartley and S. Pata, (Ed.) The Chemistry of the Metal-Carbon Bond; Wiley, Chichester 1982, p. 181.

    Google Scholar 

  5. E. O. Fischer and H. Fischer, in J. J. Zuckermann, (Ed.) The Formation of Bonds to C, Si, Ge, Sn, Pb; (Inorganic Reactions and Methods, Vol. 12b, part 4), VCH, Weinheim 1990.

    Google Scholar 

  6. H. Fischer, H. P. Volkland, A Früh and R. Stumpf, J. Organomet. Chem., 491 (1995) 267.

    Article  CAS  Google Scholar 

  7. H. Fischer, O. Podschadly, A. Früh, C. Troll, R. Stumpf and A. Schlageter, Chem. Ber., 125 (1992) 2667.

    CAS  Google Scholar 

  8. H. Fischer, A. Schlageter, W. Bidell and A. Früh, Organometallics, 10 (1991) 389.

    Article  CAS  Google Scholar 

  9. F. T. Boullet, Synthesis Commun., (1985) 679.

  10. M. B. Simpson, M. Poliakoff, J. J. Turner, W. B. Maier and J. G. McLaughlin, J. Chem. Soc. Chem. Commun., (1983) 1355.

  11. M. J. Schadt, N. J. Gresalfi and A. J. Lees, Inorg. Chem., 24 (1985) 2942.

    Article  CAS  Google Scholar 

  12. T. A. Seder, S. P. Church, A. J. Ouderkirk and E. Weitz, J. Am. Chem. Soc., 107 (1985) 1432, 108 (1986) 4721.

    Article  CAS  Google Scholar 

  13. M. M. Abd-El-Zaher El-Abiad, Characterization of some carbonyl complexes, Ph. D. Thesis, Cairo University, 1995.

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Authors and Affiliations

  1. Chemistry Department, Faculty of Science, Cairo University, Giza, A.R., Egypt

    M. A. Zayed

  2. Faculty of Chemistry, Konstanz University, University Street 10, P. Box 5560 M727, D-78434 F.R., Germany

    H. Fischer

Authors
  1. M. A. Zayed
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  2. H. Fischer
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Zayed, M.A., Fischer, H. Investigation of Novel Organometallics by Thermal Spectroscopic Methods. Journal of Thermal Analysis and Calorimetry 61, 897–908 (2000). https://doi.org/10.1023/A:1010102809977

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  • DOI: https://doi.org/10.1023/A:1010102809977

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