Abstract
The isolation and characterization of [CpRu(9S3)](O3SCF3), where 9S3 = 1,4,7-trithiacyclononane, is reported. The title compound crystallizes in the orthorhombic space group Pbca: a = 10.2542(18), b = 14.8991(13), c = 22.4832(18) Å, and Z = 8. The Ru atom is sandwiched between the π-bound cyclopentadienyl ligand and the 9S3 ligand, bonding to all three of the sulfur atoms in the 9S3. The Ru—S distances are 2.2991(10), 2.2979(11), and 2.3055(10) Å. The C—S distances range from 1.819(4) to 1.852(5) Å in the trithiacyclononane ring.
Similar content being viewed by others
References
Cordes, A.W.; Draganjac, M. Acta Crystallogr. Sect. C. 1988, C44, 363.
Draganjac, M.; Minick, D.; Cordes, A.W. J. Cryst. Spec. Res. 1993, 23, 265.
Park, H.; Minick, D.; Draganjac, M.; Cordes, A.W.; Hallford, R.L.; Eggleton, G. Inorg. Chim. Acta 1993, 204, 195.
Minick, D.; Draganjac, M.; Crump, J.W.; Cordes, A.W. J. Cryst. Spec. Res. 1993, 23, 629.
Park, H.; Minick, D.; Draganjac, M.; Crump, J.W.; Cordes, A.W.; Holt, E.M. Proc. Ark. Acad. Sci. 1993, 47, 142.
Bryan, C.D.; Cordes, A.W.; Draganjac, M. Acta Crystallogr. Sect. C. 1994, 50, 1231.
Jiang, Y.; Draganjac, M.; Cordes, A.W. J. Cryst. Chem. 1995, 25, 653.
Park, H.; Draganjac, M.; Scott, S.R.; Cordes, A.W.; Eggleton, G. Inorg. Chim. Acta 1994, 221, 157.
Jiang, Y.; Draganjac, M.; Cordes, A.W. J. Cryst. Chem. 1996, 26, 657.
Structures of the pentamethylene sulfide, 1,3-dithiane, 1,4-dithiane and 1,3,5-trithiane complexes to be published.
Adams, R.D.; Belinski, J.A.; Pompeo, M.P. Organometallics 1991, 10, 2539.
Adams, R.D.; Pompeo, M.P. Organometallics 1992, 11, 1460.
Adams, R.D.; Belinski, J.A.; Pompeo, M.P. Organometallics 1992, 11, 2016.
Adams, R.D.; Pompeo, M.P. Organometallics 1992, 11, 2281.
Adams, R.D.; Belinski, J.A. Organometallics 1992, 11, 2488.
Adams, R.D.; Belinski, J.A.; Pompeo, M.P. Organometallics 1992, 11, 3129.
Adams, R.D.; Cortopassi, J.E.; Falloon, S.B. Organometallics 1992, 11, 3794.
Adams, R.D.; Falloon, S.B. J. Am. Chem. Soc. 1994, 116, 10540.
Adams, R.D.; Falloon, S.B.; McBride, K.T.; Yamamoto, J.H. Organometallics 1995, 14, 1739.
Adams, R.D.; Falloon, S.B. Organometallics 1995, 14, 1748.
Adams, R.D.; Yamamoto, J.H. Organometallics 1995, 14, 3704.
Adams, R.D.; Falloon, S.B. Organometallics 1995, 14, 4594.
Rondon, D.; Delbeau, J.; He, X.-D.; Sabo-Etienne, S.; Chaudret, B. J. Chem. Soc. Dalton Trans. 1994, 1895.
McKinley, J.B. Catalysis V; Rheinhold: New York, 1957.
Gates, B.C.; Katzer, J.R.; Schuit, G.C.A. Chemistry of Catalytic Processes; McGraw-Hill: New York, 1979.
Bruce, M.I.; Windsor, N.J. Aust. J. Chem. 1977, 30, 1601.
Gabe, E.J.; LePage, Y.; Charland, J.P.; Lee, F.L.; White, P.S. J. Appl. Crystallogr. 1989, 22, 383.
Blake, A.J.; Crofts, R.D.; Reid, G. J. Organomet. Chem. 1989, 359, 371.
Bell, M.N.; Blake, A.J.; Schroder, M.; Kuppers, H.-J.; Wieghardt, K. Angew. Chem. Int. Ed. Engl. 1987, 26, 250.
Rawle, S.C.; Sewell, T.J.; Cooper, S.R. Inorg. Chem. 1987, 26, 3769.
Cannadine, J.C.; Hill, A.F.; White, A.J.P.; Williams, D.J.; Wilton-Ely, J. D.E.T. Organometallics 1996, 15, 5409.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Green, M., Draganjac, M., Jiang, Y. et al. Synthesis and molecular structure of [CpRu(1,4,7-S3C6H12)]O3SCF3. Journal of Chemical Crystallography 29, 273–276 (1999). https://doi.org/10.1023/A:1009561531985
Issue Date:
DOI: https://doi.org/10.1023/A:1009561531985