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Investigation of the Effect of Barium Metaphosphate Additives on the Structure of Fluoroaluminate Glasses by Optical and EPR Spectroscopy

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Abstract

Optical fluoroaluminate glasses containing 0.3–5 mol % Ba(PO3)2 have been investigated by IR and EPR spectroscopy. It is found that the PO4 2– and PO3 2– centers play the main role in the radiation processes over the entire Ba(PO3)2 concentration range under consideration. The assumption is made that the structure of fluoroaluminate glasses with small additives of Ba(PO3)2 is built up of a set of fragments that involve the [AlF6] octahedra and are linked by the P–O–P bonds.

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REFERENCES

  1. Khalilev, V.D. and Tagil'tseva, N.O., Fluorophosphate and Fluoroaluminate Optical Glasses for Microlenses, Tezisy dokl. X simpoziuma po khimii neorganicheskikh ftoridov. Ftoridnye materialy (Fluoride Materials, Abstracts of Papers, X Symp. on Chemistry of Inorganic Fluorides), Moscow: Dialog, 1998, p. 168.

    Google Scholar 

  2. Bocharova, T.V., Karapetyan, K.G., and Khalilev, V.D, Optical Glass, RF Patent 49 1831 9, S 1 SOZS 3/247, no. 2036173, Byull. Izobret., 1995, no. 15, pp. 1-3.

    Google Scholar 

  3. Khalilev, V.D., Fluorophosphate Glasses, in Svoistva i razrabotka novykh opticheskikh stekol (Properties and Development of New Optical Glasses), Leningrad: Mashinostroenie, 1977, pp. 62-90.

    Google Scholar 

  4. Khalilev, V.D., Petrovskaya, M.L., and Nikolina, G.P., Regularities of Glass Formation in Fluorine-Containing Phosphate Systems, Fiz. Khim. Stekla, 1975, vol. 1, no. 6, pp. 508-511.

    Google Scholar 

  5. Khalilev, V.D. and Anisonyan, L.B., Oxygen-Free Fluoroaluminate Glasses Based on Usovite, Fiz. Khim. Stekla, 1985, vol. 11, no. 6, pp. 734-737.

    Google Scholar 

  6. Chkhenkeli, G.D., Khalilev, V.D., Karapetyan, G.O., and Bocharova, T.V., Relaxation Processes in γ-Irradiated Glasses in the Ba(PO3)2-LiRAlF6 (where R = Mg, Ca, Sr, Ba) System, “Relaksatsionnye yavleniya v neorganicheskikh steklakh (Abstracts of Papers, All-Union Symp. “Relaxation Effects in Inorganic Glasses”), Tbilisi, 1984, pp. 81-82.

  7. Khalilev, V.D. and Bogdanov, V.L., Fluoride Glasses, Zh. Vses. Khim. O-va im. D.I. Mendeleeva, 1991, vol. 36, no. 5, pp. 593-602.

    Google Scholar 

  8. Khalilev, V.D. and Bogdanov, V.L., Fluoroaluminate Glasses, Vysokochist. Veshchestva, 1992, no. 4, pp. 110-118.

  9. Byrdin, A.N., Tekhnologiya opticheskogo stekla (Optical Glass Technology), Moscow: Vysshaya Shkola, 1963.

    Google Scholar 

  10. Bocharova, T.V., Grigoryan, T.M., Karapetyan, G.O., and Remizov, N.V., EPR, Mössbauer, and Spectral Luminescent Studies of Radiation-Resistant Fluoroaluminate Glasses, Tezisy dokl. VIII Vses. simpoziuma po khimii neorganicheskikh ftoridov (Abstracts of Papers, VIII All-Union Symp. on Chemistry of Inorganic Fluorides), Moscow: Nauka, 1987, p. 400.

    Google Scholar 

  11. Bogomolova, L.D., Caccavale, F., Tagil'tseva, N.O., etal., Study of Paramagnetic Species in γ-Irradiated Fluoride Glasses Doped with Transition Metals, J. Non-Cryst. Solids, 1999, vol. 255, nos. 2-3, p. 149-162.

    Google Scholar 

  12. Grishin, I.A., Dianov, E.M., Kiselev, N.I., et al., Radiation-induced Color Centers in Multicomponent Glasses Based on Zirconium Fluoride, Fiz. Khim. Stekla, 1984, vol. 10, no. 2, pp. 252-255.

    Google Scholar 

  13. Fisanih, O.E., Gallibarton, L.E., Fuerhelm, L.N., and Sibley, W.A., Radiation Induced Defect in Fluoride Glasses, J. Non-Cryst. Solids, 1985, vol. 70, no. 1, pp. 37-44.

    Google Scholar 

  14. Bogomolova, L.D., Teplyakov, Yu.G., Khalilev, V.D., et al., On the Formation of Radiation-induced Defects in Fluoroaluminate Glasses, Opt. Mater., 1996, no. 5, pp. 311-320.

  15. Karapetyan, G.O., Sherstyuk, A.N., and Yudin, D.M., Study of Optical and EPR Spectra of γ-Irradiated Phosphate Glasses, Opt. Spektrosk., 1967, vol. 22, no. 3, pp. 443-449.

    Google Scholar 

  16. Bocharova, T.V., Karapetyan, G.O., and Yashchurzhinskaya, O.A., On the Correlation of Optical and EPR Spectra of γ-Irradiated Activated Phosphate Glasses, Fiz. Khim. Stekla, 1985, vol. 11, no. 6, pp. 677-684.

    Google Scholar 

  17. Khalilev, V.D., Karapetyan, G.O., Bocharova, T.V., and Grigoryan, T.M., Glass for Optical Fiber, USSR Inventor's Certificate no. 1 445 125, Byull. Izobret., 1987, no. 19, p. 1-3.

  18. Grigoryan, T.M., Khalilev, V.D., Karapetyan, G.O., and Bocharova, T.V., Radiation-Chemical Study of Fluoroaluminate Glasses, in Proizvodstvo i issledovanie stekol i silikatnykh materialov (Production and Investigation of Glasses and Silicate Materials), Yaroslavl': Verkhne-Volzhskoe knizhnoe izd., 1988, issue, 9, pp. 176-179.

    Google Scholar 

  19. Bocharova, T.V., Karapetyan, G.O., Khalilev, V.D., and Yashchurzhinskaya, O.A., Optical and EPR Spectra of γ-Irradiated Glasses in the Ba(PO3)2-LaF3 System, Fiz. Khim. Stekla, 1985, vol. 11, no. 1, pp. 87-92.

    Google Scholar 

  20. Bocharova, T.V., Karapetyan, G.O., and Shelekhin, Yu.L., Paramagnetic Centers in γ-Irradiated Activated Phosphate Glasses, Fiz. Khim. Stekla, 1985, vol. 11, no. 2, pp. 233-237.

    Google Scholar 

  21. Yukhnevich, G.V., Infrakrasnaya spektroskopiya vody (IR Spectroscopy of Water), Moscow: Nauka, 1973.

    Google Scholar 

  22. Oganesyan, R.M. and Tarlakov, Yu.P., A Study of Transmission in Glasses Based on BaGeO2-CaF2 in the Range of 26 μm, Fiz. Khim. Stekla, 1985, vol. 11, no. 4, pp. 457-460.

    Google Scholar 

  23. Khalilev, V.D., Vasylyak, Ya.P., Mel'nikova, O.B., et al., IR Spectroscopic and X-ray Powder Analyses of Alkali-Free Fluorophosphate Glasses and Products of Their Crystallization, Fiz. Khim. Stekla, 1978, vol. 4, no. 1, pp. 42-46.

    Google Scholar 

  24. Kanamoto, Y. and Kono, A., Raman Spectroscopic Study of AlF3-CaF2-BaF2 Glasses, J. Non-Cryst. Solids, 1986, vol. 85, no. 3, pp. 335-345.

    Google Scholar 

  25. Karapetyan, G.O., Rusan, V.V., and Yashchurzhinskaya, O.A., Effect of Melting Conditions on the Properties of Radiation-induced Color Centers in Lanthanum Phosphate Glasses, Fiz. Khim. Stekla, 1985, vol. 11, no. 2, pp. 181-187.

    Google Scholar 

  26. Mott, N., Electrons in Vitreous Materials, Usp. Fiz. Nauk, 1979, vol. 127, no. 1, pp. 41-50.

    Google Scholar 

  27. Vil'chinskaya, N.V., Dmitryuk, A.V., Ignat'ev, E.G., etal., Mechanisms of Postradiation Transformations in Copper-activated Alkali Phosphate Glasses, Dokl. Akad. Nauk SSSR, 1984, vol. 274, no. 5, pp. 457-459.

    Google Scholar 

  28. Khalilev, V.D., Karapetyan, K.G., Bogdanov, V.L., et al., Structure and Properties of Fluorophosphate Glasses Based on Usovite, Fiz. Khim. Stekla, 1990, vol. 16, no. 4, pp. 529-533.

    Google Scholar 

  29. Nemilov, S.V., Viscosity and Structure of Glass, Stekloobraznoe sostoyanie. Tr. IV Vses. soveshchaniya (The Vitreous State, Proc. IV All-Union Conf.), Moscow: Akad. Nauk SSSR, 1965, pp. 64-65.

    Google Scholar 

  30. Nemilov, S.V., Analysis of Energy Activation Parameters and the Nature of Viscous Flow of Inorganic Glasses, in Uspekhi reologii polimerov (Advances in the Rheology of Polymers), Moscow: Khimiya, 1970, pp. 241-255.

    Google Scholar 

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Authors and Affiliations

  1. St. Petersburg State Technical University, ul. Politekhnicheskaya 29, St. Petersburg, 195251, Russia

    T. V. Bocharova & G. O. Karapetyan

  2. St. Petersburg Technological Institute (Technical University), Moskovskii pr. 26, St. Petersburg, 198013, Russia

    N. O. Tagil'tseva & V. D. Khalilev

Authors
  1. T. V. Bocharova
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  2. G. O. Karapetyan
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  3. N. O. Tagil'tseva
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  4. V. D. Khalilev
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Bocharova, T.V., Karapetyan, G.O., Tagil'tseva, N.O. et al. Investigation of the Effect of Barium Metaphosphate Additives on the Structure of Fluoroaluminate Glasses by Optical and EPR Spectroscopy. Glass Physics and Chemistry 27, 48–53 (2001). https://doi.org/10.1023/A:1009559820794

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