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X-ray structure of [Os3(CO)10(μ-Ph2PCH2PPh2)]

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Abstract

Decacarbonyl-μ-bis(diphenylphosphino)methane triosmium crystallizes in the monoclinic space group P21/c with a = 24.422(5), b = 12.381(2), c = 24.788(5) Å, β = 103.69(3)°, V = 7282 (2) Å3, and Z = 8. The molecule consists of a triangular arrangement of osmium atoms with the organic ligand bridging two adjacent osmium atoms at equatorial sites. The Os—Os distances lie in the close range 2.8563(9)–2.8895(11) Å with an average value of 2.87(1) Å.

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Authors and Affiliations

  1. Department of Chemistry, Jahangirnagar University, Savar, Dhaka, 1342, Bangladesh

    Kazi A. Azam, Shariff E. Kabir & M. Abdul Mottalib

  2. Department of Chemistry, Cardiff University, P.O. Box 912, Park Place, Cardiff, CF1 3TB

    Michael B. Hursthouse & K.M. Abdul Malik

Authors
  1. Kazi A. Azam
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  2. Michael B. Hursthouse
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  3. Shariff E. Kabir
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  4. K.M. Abdul Malik
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  5. M. Abdul Mottalib
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Azam, K.A., Hursthouse, M.B., Kabir, S.E. et al. X-ray structure of [Os3(CO)10(μ-Ph2PCH2PPh2)]. Journal of Chemical Crystallography 29, 813–818 (1999). https://doi.org/10.1023/A:1009551905096

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  • DOI: https://doi.org/10.1023/A:1009551905096

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