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Regularities of Vaporization of Periodic Table Group IVA Element Phosphates

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Abstract

The vaporization of glass-forming phosphates of the periodic table Group IVA elements is studied by high-temperature mass spectrometry. Analyses of qualitative and quantitative vapor compositions have revealed a number of regularities that allow the prediction of the character of the vaporization of polyvalent element phosphates.

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REFERENCES

  1. Bondar', I.A. and Mal'shikov, A.E., Fosfaty elementov chetvertoi gruppy (Group IV Element Phosphates), St. Petersburg: Nauka, 1992.

    Google Scholar 

  2. Bekturov, A.B., Serazetdinov, D.Z., and Urikh, V.A., Fiziko-khimicheskie osnovy polucheniya polifosfornykh udobrenii (Physicochemical Principles of Polyphosphoric Fertilizer Production), Alma-Ata: Nauka Kaz. SSR, 1979.

    Google Scholar 

  3. Tananaev, I.V., Rozanov, I.A., Avduevskaya, K.A., Beresnev, E.N., and Berdnikov, V.R., Fosfaty chetyrekhvalentnykh elementov (Tetravalent Element Phosphates), Moscow: Nauka, 1972.

    Google Scholar 

  4. Tien, T.G. and Hummel, F.A., The System SiO2-P2O5, J. Am. Ceram. Soc., 1962, vol. 45, no. 9, pp. 422-424.

    Google Scholar 

  5. Avduevskaya, K.A. and Tananaev, I.V., On Germanium Phosphate, Zh. Neorg. Khim., 1965, vol. 10, no. 2, pp. 366-371.

    Google Scholar 

  6. Huang, C.-H., Knop, O., Othen, D.A., Woodhams, F.D.W., and Howie, R.A., Phosphates of TetravaGLASS lent Elements and a Mössbauer Study of SnP2O7, Can. J. Chem., 1975, vol. 53, no. 1, pp. 79-91.

    Google Scholar 

  7. Flemish, J.R. and Tressler, R.E., PxO9 Evaporation from SiP2O7 and Its Relationship to Phosphosilicate Glass Films, J. Electrochem. Soc., 1991, vol. 138, no. 12, pp. 3743-3746.

    Google Scholar 

  8. Shultz, M.M., Stolyarova, V.L., Shornikov, S.I., Ivanov, G.G., Bondar', I.A., and Mal'shikov, A.E., Mass Spectrometric Study of Vaporization Processes and Thermodynamic Properties of GeO2-P2O5 System, in Spetsial'nye vyazhushchie i izdeliya (tekhnologiya i svoistva). Tr. Tsentral'nogo Issledovatel'skogo Inst. Stroitel'nykh Konstruktsii im. V.A. Kucherenko [Special Binders and Articles (Technology and Properties), Proc. Kucherenko Central Res. Inst. of Building Constructions], Moscow, 1992, pp. 32-46.

  9. Kambayashi, S. and Kato, E., Mass Spectrometric Determination of Activities of P2O5 in PbO-P2O5 and FetO-P2O5 Systems, J. Iron Steel Inst. Jpn., 1984, vol. 70, no. 12, p. 863.

    Google Scholar 

  10. Kambayashi, S., Awaka, H., and Kato, E., Mass Spectrometric Determination of Activities of P2O5 in PbO-P2O5 and FetO-P2O5 Systems, Tetsu-to-Hagane, 1985, vol. 71, no. 16, pp. 1911-1918.

    Google Scholar 

  11. Lopatin, S.I. and Semenov, G.A., Regularities of Vaporization of Periodic Table Group III Element Phosphates, Fiz. Khim. Stekla, 1998, vol. 24, no. 4, pp. 479-483 [Glass Phys. Chem. (Engl. transl.), 1998, vol. 24, no. 4, pp. 333-336].

    Google Scholar 

  12. Lopatin, S.I. and Semenov, G.A., Vaporization Processes in Silicon and Germanium Diphosphates, Zh. Obshch. Khim., 1995, vol. 65, no. 7, pp. 1060-1064.

    Google Scholar 

  13. Lopatin, S.I. and Semenov, G.A., Mass Spectrometric Study of Vaporization of Sn2P2O7, Zh. Obshch. Khim., 1996, vol. 66, no. 2, pp. 180-183.

    Google Scholar 

  14. Semenov, G.A., Frantseva, K.E., and Urikh, V.A., Mass Spectrometric Study of Evaporation of Lead and Bismuth Phosphates, “Fosfaty-84” (Abstracts of Papers, VI All-Union Conf. on Phosphates “Phosphates-84”), Alma-Ata, 1984, part 1, p. 202-203.

  15. Semenov, G.A. and Lopatin, S.I., Thermodynamic Properties of the Gaseous Phosphates of Germanium, Tin and Lead by the High Temperature Mass Spectrometry Method, Abstracts of Papers, XIV IUPAC Conf. on Chemical Thermodynamics), Osaka, 1996, p. 583.

  16. Energii razryva khimicheskikh svyazei. Potentsialy ionizatsii i srodstvo k elektronu. Spravochnik, (A Handbook on the Dissociation Energies of Chemical Bonds: Ionization Potentials and Electron Affinity), Kondrat'ev, V.N., Ed., Moscow: Nauka, 1974.

    Google Scholar 

  17. Alikhanyan, A.S., Steblevskii, A.S., Gorgoraki, V.I., and Sokolova, I.D., Thermodynamic Properties of Alkali Metals, Dokl. Akad. Nauk SSSR, 1975, vol. 22, no. 3, pp. 629-632.

    Google Scholar 

  18. Paule, R.C. and Mandel, J., Analysis Interlaboratory Measurements on the Vapour Pressure of Gold, Pure Appl. Chem., 1972, vol. 31, no. 3, pp. 371-394.

    Google Scholar 

  19. Vol, A.E. and Kagan, I.K., Stroenie i svoistva dvoinykh metallicheskikh sistem (Structure and Properties of Binary Metallic Systems), Moscow: Nauka, vol. 3, 1976.

    Google Scholar 

  20. Semenov, G.A., Nikolaev, E.N., and Frantseva, K.E., Primenenie mass-spektrometrii v neorganicheskoi khimii (Use of Mass Spectrometry in Inorganic Chemistry), Leningrad: Khimiya, 1976.

    Google Scholar 

  21. Kuz'menkov, M.I., Pechkovskii, V.V., and Plyshevskii, S.V., Khimiya i tekhnologiya metafosfatov (Chemistry and Technology of Metaphosphates), Minsk: Izd. Universitetskoe, 1985.

    Google Scholar 

  22. Drowart, J., Myers, C.E., Szwarc, R., van der Auwera-Mahieu A., and Uy, O.M., Determination by the Mass Spectrometry Knudsen Cell Method of the Atomization Energies of the Molecules PO and PO2, J. Chem. Soc., Faraday Trans. 2, 1972, vol. 68, no. 10, pp. 1749-1757.

    Google Scholar 

  23. Semenov, G.A., Nikolaev, E.N., Kuligina, L.A., and Frantseva, K.E., On the Temperature Coefficient of Mass Spectra of Complex Oxide Compounds, “Khimiya paroobraznykh neorganicheskikh soedinenii i protsessov paroobrazovaniya” (Abstracts of Papers, All-Union Conf. “Chemistry of Vaporous Inorganic Compounds and Vaporization Processes”), Minsk, 1976, pp. 179-181.

  24. Termodinamicheskie svoistva individual'nykh veshchestv. Spravochnik (A Handbook on the Thermodynamic Properties of Individual Compounds), Glushko, V.P., Ed., Moscow: Nauka, 1978, vol. 1, Book 2; 1979, vol. 2, Book 2.

    Google Scholar 

  25. Lopatin, S.I., Thermal Dissociation of Alkaline-Earth Metal and Magnesium Phosphates According to High-Temperature Mass Spectrometric Data, Abstract of Cand. Sc. Dissertation, Leningrad, 1990.

  26. Kazenas, E.K. and Tsvetkov, Yu.V., Isparenie oksidov (Oxide Evaporation), Moscow: Nauka, 1997.

    Google Scholar 

  27. Stolyarova, V.L., High Temperature Mass Spectrometric Study of Oxide Systems and Materials, Rapid Commun. Mass Spectrom., 1993, vol. 7, pp. 1022-1032.

    Google Scholar 

  28. Lopatin, S.I., Vaporization in Phosphate Systems, Zh. Obshch. Khim., 1997, vol. 67, no. 2, pp. 208-227.

    Google Scholar 

  29. Lopatin, S.I., Semenov, G.A., and Selevich, A.F., Vaporization of Indium Phosphates, Zh. Obshch. Khim., 1997, vol. 76, no. 11, pp. 1783-1787.

    Google Scholar 

  30. Lopatin, S.I., Thermal Dissociation of Boron and Aluminum Monophosphates, Zh. Obshch. Khim., 1997, vol. 67, no. 7, pp. 1057-1060.

    Google Scholar 

  31. Lopatin, S.I., Semenov, G.A., and Selevich, A.F., A Mass Spectrometric Study of Evaporation of Thallium Phosphate, Zh. Obshch. Khim., 1998, vol. 68, no. 6, pp. 892-894.

    Google Scholar 

  32. Lopatin, S.I., Semenov, G.A., and Selevich, A.F., Vaporization of Gallium Monophosphate According to the High-Temperature Mass Spectrometric Data, Zh. Obshch. Khim., 1999, vol. 69, no. 4, pp. 555-557.

    Google Scholar 

  33. Lopatin, S.I. and Semenov, G.A., Mass Spectrometric Study of the Vaporization of Boron Phosphate BPO4, Rapid Commun. Mass Spectrom., 1999, vol. 13, pp. 1398-1400.

    Google Scholar 

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  1. Chemistry Research Institute, St. Petersburg State University, Universitetskii pr. 2, Petrodvorets, 198904, Russia

    S. I. Lopatin & G. A. Semenov

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  1. S. I. Lopatin
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Lopatin, S.I., Semenov, G.A. Regularities of Vaporization of Periodic Table Group IVA Element Phosphates. Glass Physics and Chemistry 27, 16–21 (2001). https://doi.org/10.1023/A:1009551618976

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