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Synthesis and crystal structure of a tetranuclear manganese(IV) cluster [L4Mn4O6](ClO4)4·2H2O (L = 1,4,7-triazacyclononane)

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Abstract

A tetranuclear manganese (IV) complex, [L4Mn4O6](ClO4)4·2H2O (1), with 1,4,7-triazacyclononane (L) as the capping ligands, has been synthesized and characterized by X-ray diffraction; monoclinic, space group P21/n with a = 21.335(6) Å, b = 11.387(3) Å, c = 21.788 (6) Å, β = 111.410 (6)°, V = 4928 (2) Å, Z = 4. Each manganese atom has a distorted octahedral environment comprised of three facially coordinated amine nitrogen atoms and three oxygen atoms, and the cation is an idealized tetrahedron. The Mn4O6 4+ cation corresponds to an adamantane skeleton.

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Authors and Affiliations

  1. Department of Chemistry, University of Nankai, Tianjin, 300071, China

    Lei Zhang, Shiping Yan, Chunhui Li, Daizheng Liao, Zonghui Jiang, Peng Cheng & Genglin Wang

  2. Institute of Elemento-organic Chemistry, Nankai University, Tianjin, 300071, China

    Linhong Weng & Xuebing Leng

Authors
  1. Lei Zhang
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  2. Shiping Yan
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  3. Chunhui Li
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  4. Daizheng Liao
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  5. Zonghui Jiang
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  6. Peng Cheng
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  7. Genglin Wang
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  8. Linhong Weng
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  9. Xuebing Leng
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Zhang, L., Yan, S., Li, C. et al. Synthesis and crystal structure of a tetranuclear manganese(IV) cluster [L4Mn4O6](ClO4)4·2H2O (L = 1,4,7-triazacyclononane). Journal of Chemical Crystallography 30, 251–254 (2000). https://doi.org/10.1023/A:1009543106577

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