Abstract
The title compound [Ni(batt)2]·4H2O, in which Hbatt is 1,3-bis[3-(5-amino-1,2,4-triazolyl)]triazene, has been prepared and its crystal structure determined by X-ray diffraction methods. The compound crystallizes in the tetragonal space group I4/m (a = 10.5645(8) Å, c = 9.1336(6) Å, and Z = 2). The Ni(batt)2 molecule has local 4¯ symmetry, but it is located on a crystallographic 4/m site and is disordered over the mirror plane. The ligand batt− is tridentate with nitro-type coordination of the triazenido group and N4 coordination of the two outer triazolyl substituents. The complex has a distorted octahedral geometry with meridional configuration of the two nearly planar batt− ligands. The geometry of the tridentate cavity is examined and a comparison is made with the Ni-terpyridyl system, which shows similar coordination around the nickel center. The FTIR, micro-Raman, and UV-vis spectra are analyzed in relation with the structure.
Similar content being viewed by others
References
Moore, D.S.; Robinson, S.D. Adv. Inorg. Chem. Radiochem. 1986, 30, 1.
Vrieze, K.; Van Koten, G. In Comprehensive Coordination Chemistry; Wilkinson, G.; Gillard, R.D.; McCleverty, J.A., Eds.; Pergamon: Oxford, 1987; vol 1, pp 195–206.
Reedijk, J. In Comprehensive Coordination Chemistry; Wilkinson G.; Gillard R.D.; Mc Cleverty J.A., Eds.; Pergamon: Oxford, 1987; vol 1, pp 73–98; Steel, P.J. Coord. Chem. Rev. 1990, 106, 227.
Slangen, P.M.; van Koningsbruggen, P.J.; Goubitz, K.; Haasnoot, J.G.; Reedijk, J. Inorg. Chem. 1994, 33, 1121; van Koningsbruggen, P.J.; Gatteschi, D.; deGraaff, R.A.G.;Haasnoot, J.G.; Reedijk, J.; Zanchini, C. Inorg. Chem. 1995, 34, 5175.
Barigelletti, F.; De Cola, L.; Balzani, V.; Hage, R.; Haasnoot, J.G.; Reedijk, J.; Vos, J.G. Inorg. Chem. 1991, 30, 641; Van Diemen, J.H.; Hage, R.; Haasnoot, J.G.; Lempers H.E.B.; Reedijk, J.; Vos, J.G.; De Cola, L.; Barigelleti, F.; Balzani, V. Inorg. Chem. 1992, 31, 3518.
Hanot, V.; Robert, T. J. Coord. Chem. 1994, 32, 349.
Hanot, V.; Robert, T.; Vander Elst, L. Syn. React. Inorg. Metal-Org. Chem. 1994, 24, 1191.
Hanot, V.P.; Robert, T.D.; Kolnaar, J.; Haasnoot, J.G.; Reedijk, J.; Kooijman, H.; Spek, A.L. J. Chem. Soc. Dalton Trans. 1996, 4275.
Hanot, V.P.; Robert, T.D.; Kolnaar, J.J.A.; Haasnoot, J.G.; Kooijman, H.; Spek, A.L. Inorg. Chim. Acta 1997, 256, 327.
Hanot, V.P.; Robert T.D.; Haasnoot, J.G.; Kooijman, H.; Spek A.L. J. Chem. Crystallogr. 1998, 28, 343.
Baker, A.T.; Craig, D.C.; Rae, A.D. Aust. J. Chem. 1995, 48, 1373.
Boer, J.L.; de Duisenberg, A.J.M. Acta Crystallogr. 1984, A40, C410.
Spek, A.L. J. Appl. Crystallogr. 1988, 21, 578.
Sheldrick, G.M. SHELXS86, Program for Crystal Structure Determination; University of Göttingen: Germany, 1986.
Spek, A.L. Acta Crystallogr. 1990, A46, C34.
Sheldrick, G.M. SHELXL93, Program for crystal structure refinement; University of Göttingen: Germany, 1993.
Wilson, A.J.C., Ed; International Tables for Crystallography, Volume C; Kluwer Academic Publishers: Dordrecht, The Netherlands, 1992.
Brémard, C.; Laureyns, J.; Merlin, J.C.; Turrel, G. J. Raman Spectrosc. 1987, 18, 305.
Starova, G.L.; Frank-Kamenetskaya, O.V.; Makarskii, V.V.; Lopyrev, V.A. Sov. Phys. Crystallogr. 1980, 25, 737.
Figgis, B.N.; Kucharski, E.S.; White, A.H. Aust. J. Chem. 1983, 36, 1563.
Constable, E.C. Adv. Inorg. Chem. Radiochem. 1986, 30, 69.
Desseyn, H.O.; Fabretti, A.C.; Malavasi, W. J. Crystallogr. Spectrosc. Res. 1990, 20, 355.
Zimmerman, F.; Lippert, Th.; Beyer, Ch.; Stebani, J.; Nuyken, O.; Wokaun, A. Appl. Spectrosc. 1993, 47, 986.
Nakamoto, K. Infrared and Raman Spectra of Inorganic and Coordination Compounds; John Wiley: New York, 1986; p 452.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Hanot, V., Robert, T., Haasnoot, J. et al. Crystal structure and spectroscopic study of bis{1,3-bis[3-(5-amino-1,2,4-triazolyl)]triazenido-N′4,N2,N″4}nickel(II) tetrahydrate. Journal of Chemical Crystallography 29, 299–308 (1999). https://doi.org/10.1023/A:1009521817873
Issue Date:
DOI: https://doi.org/10.1023/A:1009521817873