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Crystal structure of methyl trans-3-[(2-(methoxycarbonyl)phenyl)sulfinyl]acrylate: a product resulting from trapping of a sulfenic acid by methyl propiolate

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Abstract

Evidence for the formation of unstable sulfenic acids (RSOH) as reaction intermediates is commonly provided by trapping these compounds with methyl propiolate. The crystal structure of a vinyl sulfoxide derived from the trapping of a sulfenic acid with methyl propiolate is reported here. The title compound C12H12O5S crystallized in the triclinic space group,P1¯ with unit cell parameters: a = 6.1600(4), b = 9.7286(7), c = 11.3698(8) Å, α = 112.024(1), β = 94.662(1), γ = 95.429(1)°, and Z = 2.

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Authors and Affiliations

  1. Department of Chemistry, University of Missouri-Columbia, Columbia, MO, 65211

    Kaushik Mitra, Charles L. Barnes & Kent S. Gates

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  1. Kaushik Mitra
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  2. Charles L. Barnes
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  3. Kent S. Gates
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Mitra, K., Barnes, C.L. & Gates, K.S. Crystal structure of methyl trans-3-[(2-(methoxycarbonyl)phenyl)sulfinyl]acrylate: a product resulting from trapping of a sulfenic acid by methyl propiolate. Journal of Chemical Crystallography 29, 1133–1136 (1999). https://doi.org/10.1023/A:1009518127038

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