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A Luminescent One-Dimensional Copper(I) Polymer

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Abstract

The synthesis and structure of a one-dimensional polymer of formula [Cu3(dpphp)2(MeCN)1.7(CH2Cl2)0.3](ClO4) n is reported (where dpphp=6-diphenylphosphino-2-pyridonate). There are three distinct copper(I) sites within the polymer. Two of these sites are four-coordinate, bound to one P- and two O-atoms and a solvate molecule; the third site is bound only to two N-atoms. The Cu*Cu distances within the polymer are around 2.8 Å. The compound is luminescent in the solid-state.

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Authors and Affiliations

  1. Department of Chemistry, University of Edinburgh, West Mains Road, Edinburgh, EH9 3JJ, UK

    Simon Parsons, Zoe Pikramenou, Gregory A. Solan & Richard E. P. Winpenny

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  1. Simon Parsons
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  2. Zoe Pikramenou
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  3. Gregory A. Solan
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  4. Richard E. P. Winpenny
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Parsons, S., Pikramenou, Z., Solan, G.A. et al. A Luminescent One-Dimensional Copper(I) Polymer. Journal of Cluster Science 11, 227–232 (2000). https://doi.org/10.1023/A:1009077118047

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  • DOI: https://doi.org/10.1023/A:1009077118047

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