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Addition of HCl to a Cluster-Bound Vinylidene Ligand: Preparation and Structure of Ru5(μ3-SMe)(μ3-CMe)(μ-Cl)(μ-SMe)(μ-PPh2)2(CO)9·PhMe

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Abstract

Addition of aqueous HCl to Ru5(μ 3-C=CH2)(μ-SMe)2(μ-PPh2)2(CO)10 afforded the structurally characterized carbyne complex Ru5(μ 3-SMe)(μ 3-CMe)(μ-Cl)(μ-SMe)(μ-PPh2)2(CO)9, formed by addition of H to the vinylidene ligand; a Cl atom bridges an Ru–Ru bond.

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Authors and Affiliations

  1. Department of Chemistry, University of Adelaide, Adelaide, South Australia, 5005

    Michael I. Bruce & Michael Schulz

  2. Department of Chemistry, University of Western Australia, Nedlands, Western Australia, 6907

    Brian W. Skelton & Allan H. White

Authors
  1. Michael I. Bruce
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  2. Michael Schulz
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  3. Brian W. Skelton
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  4. Allan H. White
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Bruce, M.I., Schulz, M., Skelton, B.W. et al. Addition of HCl to a Cluster-Bound Vinylidene Ligand: Preparation and Structure of Ru5(μ3-SMe)(μ3-CMe)(μ-Cl)(μ-SMe)(μ-PPh2)2(CO)9·PhMe. Journal of Cluster Science 11, 79–86 (2000). https://doi.org/10.1023/A:1009056513504

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  • DOI: https://doi.org/10.1023/A:1009056513504

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