Abstract
In acid sulfate solutions, the electrochemical behavior of steel ShKh15 quenched at a high ductile–brittle transition temperature (1100–1300°C) is largely defined by the content of impurities (Cr, Si, S, P) at grain boundaries, which depends on the quenching temperature. The cathodic-reaction order by hydrogen ions decreases and the anodic-reaction order by hydroxyl ions increases with increasing the content.
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Makletsov, V.G., Zabil'skii, V.V., Nikonova, R.M. et al. Electrochemical Behavior of Steel ShKh15 in Acid Sulfate Solutions as a Function of the Quenching Temperature. Russian Journal of Electrochemistry 37, 330–332 (2001). https://doi.org/10.1023/A:1009050019267
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DOI: https://doi.org/10.1023/A:1009050019267