Skip to main content
SpringerLink
Log in

Reaction of the Binuclear Ruthenium-Platinum Allenyl Complexes (PPh3)2Pt(μ-η1:η2α, β-C(R)=C=CH2)Ru(CO)Cp (R=H, Ph) with (PPh3)AuO3SCF3. The Synthesis and Characterization of a Trimetallic 1:1 Adduct of the Reactants

  • Published:
Journal of Cluster Science Aims and scope Submit manuscript

Abstract

The reaction of the heterobinuclear metal μ-allenyl complexes (PPh3)2Pt(μ-η 1:η 2 α, β -C(R)=C=CH2)Ru(CO)Cp (R=H (1), Ph (2)) with (PPh3)AuO3SCF3 in THF at −78°C to room temperature affords the trimetallic products [(PPh3)2Pt(μ 2-CO)RuCpAu(PPh3)(μ 3-η 1:η 3:η 1-CH2CCR)]+O3SCF− 3 (R=H (3), Ph (4)) in 46 and 55% isolated yield, respectively. The products were characterized by a combination of elemental analysis, FAB mass spectrometry, and IR and 1H, 13C, and 31P NMR spectroscopy. The structure of 4 was elucidated by a single-crystal X-ray analysis. The crystal contains discrete trimetallic RuPtAu cations and CF3SO− 3 anions. In the cation, a Pt–Ru bond of 2.7171(6) Å is supported by a semibridging CO and a CH2CCPh allyl, which is η 3-bonded to Ru, and η 1-bonded to each of Pt (through the CPh carbon) and Au (through the central carbon). The Ph3P–Au–C fragment is close to linear (175.0(2)°), and the coordination environment around Pt is distorted square planar. Complex 3 appears to have the same type of structure as 4 from spectroscopic data.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

REFERENCES

  1. A. Wojcicki and C. E. Shuchart (1990). Coord. Chem. Rev. 65, 219.

    Google Scholar 

  2. A. Wojcicki (1993). J. Cluster Sci. 4, 59.

    Google Scholar 

  3. S. Doherty, J. F. Corrigan, A. J. Carty, and E. Sappa (1995). Adv. Organomet. Chem. 37, 39.

    Google Scholar 

  4. A. Aime, D. Osella, L. Milone, and A. Tiripicchio (1983). Polyhedron 2, 77.

    Google Scholar 

  5. D. Nucciarone, N. J. Taylor, and A. J. Carty (1986). Organometallics 5, 1179.

    Google Scholar 

  6. A. Meyer, D. J. McCabe, and M. D. Curtis (1987). Organometallics 6, 1491.

    Google Scholar 

  7. D. Seyferth, G. B. Womack, C. M. Archer, and J. C. Dewan (1989). Organometallics 8, 430.

    Google Scholar 

  8. G. H. Young, M. V. Raphael, A. Wojcicki, M. Calligaris, G. Nardin, and N. Bresciani-Pahor (1991). Organometallics 10, 1934.

    Google Scholar 

  9. N. Carleton, J. F. Corrigan, S. Doherty, R. Pixner, Y. Sun, N. J. Taylor, and A. J. Carty (1994). Organometallics 13, 4179.

    Google Scholar 

  10. S. Ogoshi, K. Tsutsumi, M. Ooi, and H. Kurosawa (1995). J. Am. Chem. Soc. 117, 10415.

    Google Scholar 

  11. S. Doherty, M. R. J. Elsegood, W. Clegg, N. H. Rees, T. H. Scanlan, and M. Waugh (1997). Organometalics 16, 3221.

    Google Scholar 

  12. R. R. Willis, C. E. Shuchart, A. Wojcicki, A. L. Rheingold, and B. S. Haggerty (1999). Manuscript in preparation.

  13. S. Doherty, M. R. J. Elsegood, W. Clegg, and M. Waugh (1996). Organometallics 15, 2688.

    Google Scholar 

  14. S. Doherty, M. R. J. Elsegood, W. Clegg, and D. Mampe (1997). Organometallics 16, 1186.

    Google Scholar 

  15. S. Doherty, M. R. J. Elsegood, W. Clegg, M. F. Ward, and M. Waugh (1997). Organometallics 16, 4251.

    Google Scholar 

  16. S. Doherty, G. Hogarth, M. R. J. Elsegood, W. Clegg, N. H. Rees, and M. Waugh (1998). Organometallics 17, 3331.

    Google Scholar 

  17. D. F. Shriver and M. A. Drezdzon, in The Manipulation of Air-Sensitive Compounds, 2nd ed. (John Wiley and Sons, New York, 1986).

    Google Scholar 

  18. G. H. Young, R. R. Willis, A. Wojcicki, M. Calligaris, and P. Faleschini (1992). Organometallics 11, 154.

    Google Scholar 

  19. M. I. Bruce, B. K. Nicholson, and O. Bin Shawkataly (1989). Inorg. Synth. 26, 324.

    Google Scholar 

  20. D. G. Evans and D. M. P. Mingos (1982). J. Organomet. Chem. 232, 171.

    Google Scholar 

  21. M. R. Gregg, J. Powell, and J. F. Sawyer (1988). J. Organomet. Chem. 352, 357.

    Google Scholar 

  22. C. E. Shuchart, R. R. Willis, and A. Wojcicki (1992). J. Organomet. Chem. 424, 185.

    Google Scholar 

  23. F. A. Cotton (1976). Prog. Inorg. Chem. 21, 1.

    Google Scholar 

  24. M. W. Schoonover, C. P. Kubiak, and R. Eisenberg (1978). Inorg. Chem. 17, 3050.

    Google Scholar 

  25. N. Dufour, A. Schier, and H. Schmidbaur (1993). Organometallics 12, 2408 and references therein.

    Google Scholar 

  26. A. Pidcock, in E. C. Alyea and D. W. Meek (eds.), Catalytic Aspects of Metal Phosphine Complexes (American Chemical Society, Washington, D.C., 1982), p. 1 and references therein.

    Google Scholar 

  27. R. R. Willis, M. Calligaris, P. Faleschini, J. C. Gallucci, and A. Wojcicki (2000). J. Organomet. Chem., in press.

Download references

Author information

Authors and Affiliations

  1. Department of Chemistry, The Ohio State University, Columbus, Ohio, 43210

    Richard R. Willis

  2. Dipartimento di Scienze Chimiche, Università di Trieste, 34127, Trieste, Italy

    Mario Calligaris

  3. Dipartimento di Scienze Chimiche, Università di Trieste, 34127, Trieste, Italy

    Paolo Faleschini

  4. Department of Chemistry, The Ohio State University, Columbus, Ohio, 43210

    Andrew Wojcicki

Authors
  1. Richard R. Willis
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Mario Calligaris
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Paolo Faleschini
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Andrew Wojcicki
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Willis, R.R., Calligaris, M., Faleschini, P. et al. Reaction of the Binuclear Ruthenium-Platinum Allenyl Complexes (PPh3)2Pt(μ-η1:η2α, β-C(R)=C=CH2)Ru(CO)Cp (R=H, Ph) with (PPh3)AuO3SCF3. The Synthesis and Characterization of a Trimetallic 1:1 Adduct of the Reactants. Journal of Cluster Science 11, 233–242 (2000). https://doi.org/10.1023/A:1009029202117

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/A:1009029202117

Search

Navigation