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Influence of the metal function in the “one-pot” synthesis of 4-methyl-2-pentanone (methyl isobutyl ketone) from acetone over palladium supported on Mg(Al)O mixed oxides catalysts

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Abstract

Pd/Mg(Al)O samples (0.05 < Pd < 0.5 wt%) were evaluated in the gas phase reaction of acetone with hydrogen to methyl isobutyl ketone (MIBK). The catalysts were prepared by impregnating a calcined Mg–Al layered double hydroxide with Pd acetylacetonate in toluene solution. The highest selectivity to MIBK was achieved with ca. 0.2 wt% Pd and size of Pd particles of ca. 3–5 nm.

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Authors and Affiliations

  1. Laboratoire de Matériaux Catalytiques et Catalyse en Chimie Organique, UMR 5618 CNRS, ENSCM, 8, rue de l'Ecole Normale, 34296, Montpellier Cedex 5, France

    Nigamananda Das, Didier Tichit, Robert Durand, Patrick Graffin & Bernard Coq

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  1. Nigamananda Das
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  2. Didier Tichit
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  3. Robert Durand
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  4. Patrick Graffin
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  5. Bernard Coq
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Das, N., Tichit, D., Durand, R. et al. Influence of the metal function in the “one-pot” synthesis of 4-methyl-2-pentanone (methyl isobutyl ketone) from acetone over palladium supported on Mg(Al)O mixed oxides catalysts. Catalysis Letters 71, 181–185 (2001). https://doi.org/10.1023/A:1009007321914

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