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A Dumbbell Shaped Fullerene Dimer with An Inorganic Linker. Addition of C60 and Tetracyanoethylene to Ir2(CO)2Cl2(Ph2P(CH2)nPPh2)2 (n=5 or 7)

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Abstract

The centrosymmetric dimers, (η 2-C60)2Ir2(CO)2Cl2(μ-Ph2P(CH2)7PPh2)2 and (η 2-TCNE)2Ir2(CO)2Cl2(μ-Ph2P(CH2)5PPh2)2, have been prepared by the reactions of C60 with Ir2(CO)2Cl2(μ-Ph2P(CH2)7PPh2)2 and of tetracyanoethylene (TCNE) with Ir2(CO)2Cl2(μ-Ph2P(CH2)5PPh2)2, respectively. The structures of both adducts have been elucidated by single crystal X-ray diffraction studies.

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Authors and Affiliations

  1. Department of Chemistry, University of California, Davis, California, 95616

    Joong W. Lee, Marilyn M. Olmstead, Jess S. Vickery & Alan L. Balch

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  1. Joong W. Lee
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  2. Marilyn M. Olmstead
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  3. Jess S. Vickery
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  4. Alan L. Balch
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Lee, J.W., Olmstead, M.M., Vickery, J.S. et al. A Dumbbell Shaped Fullerene Dimer with An Inorganic Linker. Addition of C60 and Tetracyanoethylene to Ir2(CO)2Cl2(Ph2P(CH2)nPPh2)2 (n=5 or 7). Journal of Cluster Science 11, 67–77 (2000). https://doi.org/10.1023/A:1009004529433

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