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The Uses of Polynuclear Metal Complexes to Develop Designed Dispersions of Supported Metal Oxides: Part I. Synthesis and Characterization

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Interface Science

Abstract

One way to design a catalyst begins with a consideration of thereaction mechanism to the desired product so that only the chemistryrequired of that mechanism will be present on the surface. The reactionmechanism will suggest the structure(s) to be developed on the surface whichshould be stabilized against changes during operation. We believe that thisideal may be approached by decorating surfaces or porous powders with amonolayer of metal complexes having the desired structures. These complexesmay be partially decomposed to develop a high dispersion of the supportedmetal oxide.

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Authors and Affiliations

  1. Laboratory of Inorganic Chemistry, University of Antwerp (U.I.A.), Universiteitsplein 1, B-2610, Wilrijk, Belgium

    Pascal Van Der Voort

  2. Department of Chemistry, Clark Atlanta University, Atlanta, GA, 30310, United States of America

    Mark B. Mitchell

  3. Laboratory of Inorganic Chemistry, University of Antwerp (U.I.A.), Universiteitsplein 1, B-2610, Wilrijk, Belgium

    Etienne F. Vansant

  4. Focused Research Program in Surface Science and Catalysis, School of Chemical Engineering, Georgia Institute of Technology, Atlanta, Ga, 30332-0100, United States of America

    Mark G. White

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  1. Pascal Van Der Voort
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  3. Etienne F. Vansant
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  4. Mark G. White
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Voort, P.V.D., Mitchell, M.B., Vansant, E.F. et al. The Uses of Polynuclear Metal Complexes to Develop Designed Dispersions of Supported Metal Oxides: Part I. Synthesis and Characterization. Interface Science 5, 169–197 (1997). https://doi.org/10.1023/A:1008669528505

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