Abstract
A theoretical full-relaxation matrix analysis of heteronuclear Overhauser effects in oligosaccharides is described. This analysis predicts that trans-glycosidic heteronuclear 1H{13C} NOEs should be measurable in a model disaccharide with appropriate enrichment with 13C and 2H. These predictions are confirmed experimentally, and the value of these measurements is discussed for conformational analysis.
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Kiddle, G.R., Harris, R. & Homans, S.W. Heteronuclear Overhauser effects in carbohydrates. J Biomol NMR 11, 289–294 (1998). https://doi.org/10.1023/A:1008216712371
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DOI: https://doi.org/10.1023/A:1008216712371