Abstract
The starburst(PAMAM)dendrimer of generation 0 was reacted with pentaammine-triflato-chromium(III) and -cobalt(III). The products were separated by ion exchange chromatography and characterized by elemental analysis, UV-VIS-, IR-, 13C-spectroscopy or cyclic voltammetry. The dendrimer forms five membered chelate rings containing amine and amide nitrogens and binds one or two metal ions.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
M. F. Ottaviani, S. Bossmann, N. J. Turro, and D. A. Tomalia: J. Am. Chem. Soc. 116, 661 (1994).
G. Wilkinson, R. D. Gillard, and J. A. Mc Clerverty: Comprehensive Coordination Chemistry, v. 4, pp. 682–684 Pergamon Press (1987), and further references given there.
N. E. Dixon, G. A. Lawrance, P. A. Lay, and A. M. Sargeson: Inorg. Chem. 23, 2940 (1984).
I. G. Browning, R. D. Gillard, J. R. Lyons, P. R. Mitchell, and D. A. Phipps: J. Chem. Soc. Dalton Trans. 1815 (1972).
E. J. Evans, C. H. Hawkins, J. Rodgers, and M. R. Snow: Inorg. Chem. 22, 34 (1983).
S. Fujii, N. Tatsumoto, and K. Yamaoka: J. Electroanal. Chem. 16, 193 (1986).
I. Tabakovic, L. L. Miller, R. G. Duan, D. C. Tully, and D. A. Tomalia: Chem. Mater. 9, 736 (1997).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Jendrusch-Borkowski, B., Awad, J. & Wasgestian, F. Reactions of Chromium(III)- and Cobalt(III)-amine-complexes with Starburst(PAMAM)dendrimers. Journal of Inclusion Phenomena 35, 355–359 (1999). https://doi.org/10.1023/A:1008123821457
Issue Date:
DOI: https://doi.org/10.1023/A:1008123821457