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A Simple Correlation between the Structures of Different Crystal Modifications of a Given Host–Guest Complex and their Crystallization Temperatures

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Abstract

The formation of different crystal modifications of a given host-guest complex depending on the crystallization temperature (pseudopolymorphism) is studied. It is shown that such pseudopolymorphism is a characteristic feature of versatile host compounds. A very important rule for host-guest chemistry is derived from the results of the X-ray structural investigations of pseudopolymorphs: the higher the crystallization temperature of the modification the more closed is the space occupied by guest molecules. On the basis of the formulated rule a recommendation for the topological control and solution of some central problems of supramolecular chemistry is proposed.

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  1. Institute of Bioorganic Chemistry, H. Abdullaev Str., 83, Tashkent, 700143, Uzbekistan

    Bakhtiyar Ibragimov

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  1. Bakhtiyar Ibragimov
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Ibragimov, B. A Simple Correlation between the Structures of Different Crystal Modifications of a Given Host–Guest Complex and their Crystallization Temperatures. Journal of Inclusion Phenomena 34, 345–353 (1999). https://doi.org/10.1023/A:1008029808197

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