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13-Membered Azocrown Ether. Structure of the Lithium Bromide Complex and Membrane Properties

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Abstract

The lithium bromide hydrate complex ofthe 13-membered dibenzoazocrown ether of composition{[LiL13(H2O)]Br}2 has been synthesized. Its structure has been determined by the X-ray method. Thecrystals are monoclinic, space group C2/c, a =12.720(6), b = 19.969(9), c = 13.963(6)Å; β = 104.32(2)°. Selectivities of membraneelectrodes based on 13-membered azocrown ethers arediscussed in terms of complex stabilities and metalcation extractabilities as related to the structuresof the respective complexes.

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Authors and Affiliations

  1. Department of Chemical Technology, Technical University of Gdańsk, 80-952 Gdańsk, Poland

    E. Luboch & J. F. Biernat

  2. Institute of Applied Physics, Academy of Sciences of Moldova, Kishinev, Moldova

    V. Ch Kravtsov & Yu. A. Simonov

Authors
  1. E. Luboch
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  2. J. F. Biernat
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  3. V. Ch Kravtsov
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  4. Yu. A. Simonov
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Luboch, E., Biernat, J.F., Kravtsov, V.C. et al. 13-Membered Azocrown Ether. Structure of the Lithium Bromide Complex and Membrane Properties. Journal of Inclusion Phenomena 31, 109–118 (1998). https://doi.org/10.1023/A:1007940713524

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